Carbonado

Carbonado, commonly known as black diamond, is one of the toughest forms of natural diamond. It is an impure form of polycrystalline diamond consisting of diamond, graphite, and amorphous carbon.[1] It is found primarily in alluvial deposits in the Central African Republic and in Brazil. Its natural colour is black or dark grey, and it is more porous than other diamonds.

For other uses, see Carbonado (disambiguation).
"Black diamonds" redirects here. For other uses, see Black Diamond.
Carbonado
Three carbonados from the Central African Republic
General
CategoryNative minerals
Formula
(repeating unit)		C
Crystal systemIsometric-hexoctahedral (cubic)
Identification
Formula mass12.01 u
ColorTypically black, can be grey, various shades of green and brown sometimes mottled.
Crystal habitPolycrystalline
FractureIrregular torn surfaces
Mohs scale hardness10
LusterAdamantine
StreakWhite
Specific gravity3.52±0.01
Density3.5–3.53 g/cm3
Polish lusterAdamantine
BirefringenceNone
PleochroismNone

Unusual properties

Carbonado diamonds are typically pea-sized or larger porous aggregates of many tiny black crystals. The most characteristic carbonados have been found only in the Central African Republic and in Brazil, in neither place associated with kimberlite, the source of typical gem diamonds. Lead isotope analyses have been interpreted as documenting crystallization of carbonados about 3 billion years ago. The carbonados are found in younger sedimentary rocks.[2]

Mineral grains included within diamonds have been studied extensively for clues to diamond origin. Some typical diamonds contain inclusions of common mantle minerals such as pyrope and forsterite, but such mantle minerals have not been observed in carbonado. In contrast, some carbonados contain inclusions of minerals characteristic of the Earth's crust; the inclusions do not necessarily establish formation of the diamonds in the crust, but because while the obvious crystal inclusions occur in the pores that are common in carbonados, they may have been introduced after carbonado formation. Inclusions of other minerals, rare or nearly absent in the Earth's crust, are found at least partly incorporated in diamond, not just in pores: among such other minerals are those with compositions of Si, SiC, and Fe‑Ni. No distinctive high-pressure minerals, including the hexagonal carbon polymorph, lonsdaleite, have been found as inclusions in carbonados although such inclusions might be expected if carbonados formed by meteorite impact.[2]

Isotope studies have yielded further clues to carbonado origin. The carbon isotope value is very low (little carbon‑13 compared to carbon‑12, relative to typical diamonds).[2]

Carbonado exhibits strong luminescence (photoluminescence and cathodoluminescence) induced by nitrogen and by vacancies existing in the crystal lattice. Luminescence halos are present around radioactive inclusions, and it is suggested that the radiation damage occurred after formation of the carbonados,[3] an observation perhaps pertinent to the radiation hypothesis listed below.

Theories on origin

The origin of carbonado is controversial, and some proposed hypotheses are as follows:

  1. Direct conversion of organic carbon under high-pressure conditions in the Earth's interior, the most common hypothesis for diamond formation
  2. Shock metamorphism induced by meteoritic impact at the Earth's surface
  3. Radiation-induced diamond formation by spontaneous fission of uranium and thorium
  4. Formation inside an earlier-generation giant star in our area, that long ago exploded in a supernova.[4]
  5. An origin in interstellar space, due to the impact of an asteroid, rather than being thrown from within an exploding star.[4]

None of these hypotheses for carbonado formation had come into wide acceptance in the scientific literature by 2008.[5]

Extraterrestrial origin hypothesis

Supporters of an extraterrestrial origin of carbonados propose that their material source was a supernova which occurred at least 3.8 billion years ago.[6][7] After coalescing and drifting through outer space for about one and a half billion years, a large mass fell to earth as a meteorite approximately 2.3 billion years ago. It possibly fragmented during entry into the Earth's atmosphere and impacted in a region which would much later split into Brazil and the Central African Republic, the only two known locations of carbonado deposits.

See also

References
  1. Kroschwitz], [executive editor, Jacqueline I. (2004). Kirk-Othmer encyclopedia of chemical technology (5th ed.). Hoboken, N. J.: J. Wiley. p. 10. ISBN 9780471484943.
  2. Heaney, P. J.; Vicenzi, E. P.; De, S. (2005). "Strange Diamonds: the Mysterious Origins of Carbonado and Framesite". Elements. 1 (2): 85. doi:10.2113/gselements.1.2.85.
  3. Kagi, H., Sato, S., Akagi, T., and Kanda, H., 2007 (2007). "Generation history of carbonado inferred from photoluminescence spectra, cathodoluminescence imaging, and carbon-isotopic composition" (PDF). American Mineralogist. 92: 217–224. Bibcode:2007AmMin..92..217K. doi:10.2138/am.2007.1957.CS1 maint: multiple names: authors list (link)
  4. Garai, Jozsef; Haggerty, Stephen E.; Rekhi, Sandeep; Chance, Mark (2006). "Infrared Absorption Investigations Confirm the Extraterrestrial Origin of Carbonado Diamonds". The Astrophysical Journal. 653 (2): L153. arXiv:physics/0608014. Bibcode:2006ApJ...653L.153G. doi:10.1086/510451. Archived from the original on 2007-08-09.. This study suggested that infrared absorption spectra of carbonado are like those of diamonds of extraterrestrial origin; the significant peaks are due to trace abundances of the elements nitrogen and hydrogen. The researchers concluded that the mineral formed in an interstellar environment. In this sense, carbonado are theorized to be akin to carbon-rich cosmic dust, likely having formed in an environment near carbon stars. The diamonds were suggested to have been fragments of a body of asteroid size that subsequently fell to Earth as meteorites.
  5. Rondeau, B; Sautter, V; Barjon, J (2008). "New columnar texture of carbonado: Cathodoluminescence study". Diamond and Related Materials. 17 (11): 1897. Bibcode:2008DRM....17.1897R. doi:10.1016/j.diamond.2008.04.006.
  6. Broad, William J. (1996-09-17). "Giant Black Diamonds Of Mysterious Origin May Hail From Space". The New York Times. ISSN 0362-4331. Retrieved 2016-09-20.
  7. Garai, Jozsef; Haggerty, Stephen E.; Rekhi, Sandeep; Chance, Mark (2006-12-20). "Infrared Absorption Investigations Confirm the Extraterrestrial Origin of Carbonado-Diamonds". The Astrophysical Journal. 653 (2): L153–L156. arXiv:physics/0608014. Bibcode:2006ApJ...653L.153G. doi:10.1086/510451. ISSN 0004-637X.
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