Contact explosive

A contact explosive is a chemical substance that explodes violently when it is exposed to a relatively small amount of energy (friction, pressure, sound, light). Though different substances have varying amounts of energy sensitivity, they are all much more sensitive relative to other explosives. Contact explosives are a part of a group of explosives called primary explosives which are also very sensitive to stimuli but not to the degree of contact explosives. The extreme sensitivity of contact explosives is due to either its composition, bonds, or structure.

Types

These are some common contact explosives.

Compound Sensitivity Sensitive to Type of explosion
Acetone peroxide High Heat, flame, shock, friction Entropic
Chlorine azide[1] Extreme Friction, shock, chemicals Energy, entropic
Copper(II) azide Extreme Shock, static Energy
Fulminates Very high Friction, static, heat, flame, shock Energy
Lead(II) azide Very high Shock, static Energy
Nitrogen triiodide Extreme [2] Shock, alpha radiation Energy, entropic
Nitroglycerin Very high Shock, friction Energy, entropic
Picric acid (dry) High Shock, friction Energy
Tetrasulfur tetranitride Moderate Shock, friction Energy, entropic
Flash powder High Static, flame, friction Energy, light
Silver nitride Extreme Shock Energy

Reasons for instability

Composition
N2 molecule

Presence of nitrogen

Explosives that are nitrogen-based are incredibly volatile due to the stability of nitrogen in its diatomic state, N2.[3][4] Most organic explosives are explosive because they contain nitrogen. They are defined as nitro compounds.

Nitro compounds are explosive because although the diatomic form of nitrogen is very stable - that is, the triple bond that holds N2 together is very strong, and therefore has a great deal of bond energy - the nitro compounds themselves are unstable, as the bonds between nitrogen atoms and other atoms in nitro compounds are weak by comparison. Therefore, little energy is required to overcome these weak bonds, but a great deal of energy is released when the strong triple bonds in N2 are formed. The rapidity of the reaction, due to the weakness of the bonds in nitro compounds, and the high quantity of overall energy released, due to the much higher strength of the triple bonds, produce the explosive qualities of these compounds.

Oxidizer and fuel

Some contact explosives contain an oxidizer and a fuel in their composition.[4] Chemicals like gasoline, a fuel, burn instead of explode because they must come into contact with oxygen in the combustion reaction. However, if the compound already contains both the oxidant and fuel, it produces a much faster and violent reaction.

Nitrogen triiodide atomic shape

Bonds and structure

The structures and bonds that make up a contact explosive contribute to its instability. Covalent compounds that have a large unequal sharing of electrons have the capability to fall apart very easily and explosively. Nitrogen triiodide is a perfect example of this property. The three huge iodine atoms try to attach themselves to one small nitrogen ion, which means that the atoms are holding on to each other through a very weak bond. The weak bond between each atom is like a thread just waiting to break. Therefore, any small amount of applied energy cuts this thread and releases the iodine and nitrogen atoms to react with the fuel, allowing the reaction to occur quickly and release a large amount of energy.[2]

The shape of the contact explosive molecule plays a role in its instability as well. Using nitrogen triiodide as an example again, its pyramidal shape forces the three iodine atoms to be incredibly close to each other. The shape further strains the already weak bonds that holds together this molecule.

Compound Reason for instability
Acetone peroxide Composition allows for initiation reaction
Chlorine azide Nitrogen
Copper(II) azide Nitrogen
Fulminates Instability of fulminate ion
Lead(II) azide Nitrogen
Nitrogen triiodide Unstable intramolecular bonds
Nitroglycerin Nitrogen, Oxidizer and fuel
Picric acid (dry) Nitrogen
Tetrasulfur tetranitride Nitrogen, Unstable intramolecular bonds
Flash Powder Oxidizer and metallic fuel
Silver nitride Unstable intramolecular bonds

Uses

Contact explosives are used in a variety of fields.

Picric acid molecule
Stun grenade

Military

Militaries use a variety of contact explosives in combat. Some can be manufactured into different types of bombs, tactical grenades, and even explosive bullets. Dry picric acid, which is more powerful than TNT, was used in blasting charges and artillery shells. A lot of contact explosives are used in detonators. For explosives that use secondary explosives, contact explosives are used in the detonators to set off an energy chain reaction that will eventually set off the secondary explosive.

Compounds like lead azide are used to manufacture bullets that explode into shrapnel on impact.

Flash powders are used in a variety of military and police tactical pyrotechnics.[5] Stun grenades, flash bangs, and flares all use flash powder to create bright, flashing lights and loud noise that disorients the enemy.

On the other hand, many of these cheap, volatile contact explosives are also used in improvised explosive devices (IEDs) created by terrorists and suicide bombers.[6] For example, acetone peroxide passes through explosive detectors and is incredibly powerful, unstable, and deadly. Evidence for the instability of these IEDs lies in the multiple reports of premature or wrongful IED explosions. However, when these explosives are used correctly, they have devastating consequences. The July 7th, 2005, London bombings, the 2015 Paris attacks, and the 2016 Brussels bombings all used explosives that contained acetone peroxide.

Medicine

Angina pectoris, an unfortunate symptom of Ischaemic heart disease, is treated with nitroglycerin.[7] Nitroglycerin is known as a vasodilator. Vasodilators work by relaxing the heart's blood vessels so the heart does not need to work as hard. Picric acid specifically has been used for burn treatment and as an Antiseptic.[8]

Theatrical/fireworks

The same flash powder used for military tactical pyrotechnics can also be used for several theatrical special effects.[9] They are used to produce loud, bright flashes of light for effect. Though some flash powders are too volatile and dangerous to be safely used, there are milder compounds that are still incorporated into performances today.

Silver Fulminate is used to make noise-makers, small contact poppers, and several other novelty fireworks.[10] It is most widely used in bang snaps. In these small explosives, a minuscule amount of silver fulminate is encased in gravel and cigarette paper. Even with this small amount of silver fulminate, it produces a loud, sharp bang.

See also

References
  1. Frierson, W. Joe, J. Kronrad, and A. W. Browne. "Chlorine Azide, CIN3. I1." - Journal of the American Chemical Society (ACS Publications). N.p., n.d. Web. 23 Oct. 2016.
  2. TheRoyalInstitution. "Slow Motion Contact Explosive - Nitrogen Triiodide." YouTube. YouTube, 27 Aug. 2015. Web. 09 Oct. 2016.
  3. "Nitro Compound." Wikipedia. Wikimedia Foundation, n.d. Web. 23 Oct. 2016.
  4. Senese, Fred. "Why Is Nitroglycerin Explosive?" General Chemistry Online: FAQ: Redox Reactions:. N.p., n.d. Web. 09 Oct. 2016.
  5. Cops, By. "Flash Bang 101." PoliceOne. N.p., n.d. Web. 04 Nov. 2016.
  6. Mosher, Dave. "The Homemade Explosive Used in the Paris Attacks Is a Chemical Nightmare." Business Insider. Business Insider, Inc, 16 Nov. 2015. Web. 01 Nov. 2016.
  7. "Nitroglycerin Sublingual: MedlinePlus Drug Information." Nitroglycerin Sublingual: MedlinePlus Drug Information. N.p., n.d. Web. 01 Nov. 2016.
  8. "Picric Acid for Severe Burns." Welcome. N.p., n.d. Web. 01 Nov. 2016.
  9. http://www.theatrefx.com/flash-powder.html
  10. Admin. "Bang-Snaps and Silver Fulminate." Bang-Snaps and Silver Fulminate. N.p., n.d. Web. 04 Nov. 2016.
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