Erythrite
Erythrite or red cobalt is a secondary hydrated cobalt arsenate mineral with the formula Co
3(AsO
4)
2•8H
2O. Erythrite and annabergite, chemical formula (Ni
3As
4)
2•8H
2O, or nickel arsenate form a complete series with the general formula (Co,Ni)
3(AsO
4)
2•8H
2O.
Erythrite | |
---|---|
Erythrite crystals | |
General | |
Category | Arsenate mineral Vivianite group |
Formula (repeating unit) | Co3(AsO4)2·8H2O |
Strunz classification | 8.CE.40 |
Dana classification | 40.03.06.03 |
Crystal system | Monoclinic |
Crystal class | Prismatic (2/m) (same H-M symbol) |
Space group | C2/m |
Identification | |
Color | Crimson to peach-red, pale rose, or pink, may be zoned |
Crystal habit | Radial or stellate aggregates, fibrous, drusy; usually powdery and massive - rarely as striated prismatic crystals |
Cleavage | Perfect on {010}; poor on {100} and {102}. |
Tenacity | Sectile |
Mohs scale hardness | 1.5 - 2.5 |
Luster | Subadamantine, pearly on cleavages |
Streak | Pale red to pink |
Diaphaneity | Transparent to translucent |
Specific gravity | 3.06 |
Optical properties | Biaxial (+) |
Refractive index | nα = 1.626 - 1.629 nβ = 1.662 - 1.663 nγ = 1.699 - 1.701 |
Birefringence | δ = 0.073 |
Pleochroism | Visible: X = pale pinkish to pale rose; Y = pale violet to pale violet-rose; Z = deep red |
References | [1][2][3] |
Erythrite crystallizes in the monoclinic system and forms prismatic crystals. The color is crimson to pink and occurs as a secondary coating known as cobalt bloom on cobalt arsenide minerals. Well-formed crystals are rare, with most of the mineral manifesting in crusts or small reniform aggregates.
Erythrite was first described in 1832 for an occurrence in Grube Daniel, Schneeberg, Saxony,[3] and takes its name from the Greek έρυθρος (erythros), meaning red.[2] Historically, erythrite itself has not been an economically important mineral, but the prospector may use it as a guide to associated cobalt and native silver.
Erythrite occurs as a secondary mineral in the oxide zone of Co–Ni–As bearing mineral deposits. It occurs in association with cobaltite, skutterudite, symplesite, roselite-beta, scorodite, pharmacosiderite, adamite, morenosite, retgersite, and malachite.[1]
Notable localities are Cobalt, Ontario; La Cobaltera, Chile, Schneeberg, Saxony, Germany; Joachimsthal, Czech Republic; Cornwall, England; Bou Azzer, Morocco; the Blackbird mine, Lemhi County, Idaho; Sara Alicia mine, near Alamos, Sonora, Mexico; Mt. Cobalt, Queensland and the Dome Rock copper mine, Mingary, South Australia.[1]
Other varieties
The nickel variety, annabergite, occurs as a light green nickel bloom on nickel arsenides. In addition iron, magnesium and zinc can also substitute for the cobalt position, creating three other minerals: parasymplesite (Fe), hörnesite (Mg) and köttigite (Zn).
References
- http://rruff.geo.arizona.edu/doclib/hom/erythrite.pdf Handbook of Mineralogy
- http://www.mindat.org/min-1407.html Mindat.org
- http://webmineral.com/data/Erythrite.shtml Webmineral data
- Dana's Manual of Mineralogy ISBN 0-471-03288-3
- Manual of Mineral Science, 22nd Ed. C. Klein.ISBN 0-471-25177-1
- Faye, G H; Nickel, E H (1968). "The origin of pleochroism in erythrite" (PDF). The Canadian Mineralogist. 9: 492–504.
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