Ethyl benzoate

Ethyl benzoate, C9H10O2, is the ester formed by the condensation of benzoic acid and ethanol. It is a colorless liquid that is almost insoluble in water, but miscible with most organic solvents.

Ethyl benzoate
Names
Preferred IUPAC name
Ethyl benzoate
Identifiers
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.002.078
EC Number
  • 202-284-3
UNII
Properties
C9H10O2
Molar mass 150.177 g·mol−1
Appearance colorless liquid
Density 1.050 g/cm3
Melting point −34 °C (−29 °F; 239 K)
Boiling point 211–213 °C (412–415 °F; 484–486 K)
0.72 mg/mL
log P 2.64
−93.32×10−6 cm3/mol
Hazards
GHS pictograms
GHS Signal word Warning
H315, H319, H411
P264, P273, P280, P302+352, P305+351+338, P321, P332+313, P337+313, P362, P391, P501
Related compounds
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

As with many volatile esters, ethyl benzoate has a pleasant odor described as sweet, wintergreen, fruity, medicinal, cherry, and grape.[1] It is a component of some fragrances and artificial fruit flavors.

Preparation

A simple and commonly used method for the preparation of ethyl benzoate in laboratory is the acidic esterification of benzoic acid with ethanol and sulfuric acid as catalyst:[2]

References

  1. Ethyl benzoate, thegoodscentscompany.com
  2. Arthur Israel Vogel. Rev. by Brian S. Furniss: Vogel’s textbook of practical organic chemistry. 5. Auflage. Longman, Harlow 1989, ISBN 0-582-46236-3, S. 1076
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