Gadolinite

Gadolinite, sometimes known as ytterbite, is a silicate mineral consisting principally of the silicates of cerium, lanthanum, neodymium, yttrium, beryllium, and iron with the formula (Ce,La,Nd,Y)
2FeBe
2Si
2O
10. It is called gadolinite-(Ce) or gadolinite-(Y), depending on the prominent composing element (Y if yttrium predominates, and Ce if cerium). It may contain 35.5% yttria sub-group rare earths, 2.2% ceria earths, as much as to 11.6% BeO, and traces of thorium. It is found in Sweden, Norway, and the US (Texas and Colorado).

Gadolinite
Gadolinite (black portion at top)
General
CategoryNesosilicate
Formula
(repeating unit)		(Ce,La,Nd,Y)
2FeBe
2Si
2O
10
Strunz classification9.AJ.20
Crystal systemMonoclinic
Crystal classPrismatic (2/m)
(same H-M symbol)
Space groupP21/n

Characteristics

Gadolinite is fairly rare and typically occurs as well-formed crystals. It is nearly black in color and has a vitreous luster. The hardness is between 6.5 and 7 on the Mohs scale, and the specific gravity is between 4.0 and 4.7. It fractures in a conchoidal pattern and streaks grayish-green. It was also thought to exhibit pyrognomic properties, as it can emit visible light when heated to relatively low temperatures, but the scientific consensus is that this is the product of thermoluminescence[1][2]

Name and discovery

Gadolinite was named in 1800 for Johan Gadolin, the Finnish mineralogist-chemist who first isolated an oxide of the rare-earth element yttrium from the mineral in 1792. The rare earth gadolinium was also named for him. However, gadolinite does not contain more than trace amounts of gadolinium. When Gadolin analyzed this mineral, he missed an opportunity to discover a second element: the element he thought was aluminium (alumina) was in fact beryllium (beryllia), an element that was not officially identified until 1798.

Uses

Gadolinite and euxenite are quite abundant and are future sources of yttrium sub group rare earths. At present, these elements are recovered from monazite concentrates (after recovery of ceria sub-group metals).

See also

References
  1. https://pubs.usgs.gov/bul/1064/report.pdf
  2. Schwartz K., Lang M. (2016) Mineral Defects. In: White W. (eds) Encyclopedia of Geochemistry. Encyclopedia of Earth Sciences Series. Springer, Cham
This article is issued from Wikipedia. The text is licensed under Creative Commons - Attribution - Sharealike. Additional terms may apply for the media files.