Iodate fluoride

The iodate fluorides are chemical compounds which contain both iodate and fluoride anions (IO3− and F−). In these compounds fluorine is not bound to iodine as it is in fluoroiodates.

List
name formula weight system space group unit cell volume density properties ref
yttrium diiodate fluoride Y(IO3)2F 457.71 hexagonal P63 a=6.8455 c=21.807 Z=6 885.0 5.153 white [1]
tin difluoride diiodate Sn(IO3)2F2 506.49 monoclinic P21 a=5.436 b=9.91 c=6.28 β=105.44 Z=2 326.3 5.155 band gap 4.08 SHG 3x; white [2]
CsVO2F(IO3) 409.75 orthorhombic Pna21 a=7.8974 b=10.2644 c=7.3854 Z=4 598.68 4.546 [3]
Barium iodate fluoride Ba(IO3)F 331.24 monoclinic P21/c a=10.5729 b=6.3354 c=6.0450 β=90.497° 404.90 5.434 band gap 4.32 eV; high birefringence [4]
α-Ba[VFO2(IO3)2] 589.08 Orthorhombic Pbcn a=5.1494 b=12.644 c=12.400 Z=4 807.4 4.846 colourless [5]
β-Ba[VFO2(IO3)2] 589.08 Orthorhombic P212121 a=7.1902 b=8.1964 c=13.0420 Z=4 768.6 5.091 colourless [5]
α-Ba2[VO2F2(IO3)2]IO3 920.32 Orthorhombic Pna21 a =13.578 b=11.425 c=7.500 Z=4 1163.5 5.254 colourless [5]
β-Ba2[VO2F2(IO3)2]IO3 920.32 monoclinic P21 a=7.3895 b=7.4994 c=10.9095 β=105.461 Z=2 582.69 5.245 colourless [5]
α-Ba2[GaF4(IO3)2](IO3) 945.10 orthorhombic Pna21 a=13.6984 b=11.3696 c=7.4245 Z=4 1156.76 5.429 colourless SHG 6×KDP band gap 4.61eV [6]
β-Ba2[GaF4(IO3)2](IO3) 945.10 monoclinic P21 a=7.4631 b=7.4511 c=10.9597 β=106.138 =2 585.24 5.361 colourless SHG 6×KDP band gap 4.35 [6]
Ce(IO3)2F2·H2O 545.94 orthorhombic Ima2 a=7.702 b=12.277 c=7.947 Z=4 751.4 4.826 light yellow [7]
K5(W3O9F4)(IO3) 1141.95 monoclinic Pm a=9.7129 b=3.7122 c=10.9575 β=102.007 Z=1 386.44 4.907 SHG 11×KDP [8]
Bi(IO3)F2 421.88 monoclinic C2 a=12.827 b=5.3089 c=6.0790 β=101.384 Z=4 405.89 6.904 SHG 11.5×KDP [9]
Bi3OF3(IO3)4 1399.54 hexagonal P63mc a=10.880 c=6.993 716.8 6.484 colourless SHG [10]
NH4Bi2(IO3)2F5 880.80 monoclinic P21 a=5.718 b=5.892 c=15.18 β=100.38 Z=2 502.9 5.817 SHG 9.2×KDP
KBi2(IO3)2F5 901.86 monoclinic P21 a=5.687 b=5.864 c=14.82 β=100.095 Z=2 486.5 6.157 colourless SHG [11]
RbBi2(IO3)2F5 948.23 monoclinic P21 a=5.7357 b=5.9095 c=15.177 β=100.263 Z=2 506.2 6.221 colourless SHG [11]
CsBi2(IO3)2F5 995.67 monoclinic P21 a=5.750 b=5.924 c=15.640 β=100.509 Z=2 523.8 6.313 colourless SHG [11]

References
  1. Peng, Guang; Yang, Yi; Yan, Tao; Zhao, Dan; Li, Bingxuan; Zhang, Ge; Lin, Zheshuai; Ye, Ning (2020). "Helix-constructed polar rare-earth iodate fluoride as a laser nonlinear optical multifunctional material". Chemical Science. 11 (28): 7396–7400. doi:10.1039/D0SC02789H. ISSN 2041-6520.
  2. Luo, Min; Liang, Fei; Hao, Xia; Lin, Donghong; Li, Bingxuan; Lin, Zheshuai; Ye, Ning (2020-03-24). "Rational Design of the Nonlinear Optical Response in a Tin Iodate Fluoride Sn(IO 3 ) 2 F 2". Chemistry of Materials. 32 (6): 2615–2620. doi:10.1021/acs.chemmater.0c00196. ISSN 0897-4756.
  3. Chen, Jin; Hu, Chun‐Li; Zhang, Xiao‐Han; Li, Bing‐Xuan; Yang, Bing‐Ping; Mao, Jiang‐Gao (2020-03-23). "CsVO 2 F(IO 3 ): An Excellent SHG Material Featuring an Unprecedented 3D [VO 2 F(IO 3 )] − Anionic Framework". Angewandte Chemie International Edition. 59 (13): 5381–5384. doi:10.1002/anie.202000587. ISSN 1433-7851. PMID 32027081.
  4. Fan, Huixin; Peng, Guang; Lin, Chensheng; Chen, Kaichuang; Yang, Shunda; Ye, Ning (13 May 2020). "Ba(IO3)F: An Alkaline-Earth-Metal Iodate Fluoride Crystal with Large Band Gap and Birefringence". Inorganic Chemistry. 59 (11): 7376–7379. doi:10.1021/acs.inorgchem.0c00945. PMID 32401023.
  5. Yu, Hongwei; Nisbet, Matthew L.; Poeppelmeier, Kenneth R. (2018-07-18). "Assisting the Effective Design of Polar Iodates with Early Transition-Metal Oxide Fluoride Anions". Journal of the American Chemical Society. 140 (28): 8868–8876. doi:10.1021/jacs.8b04762. ISSN 0002-7863. PMID 29893564.
  6. Chen, Jin; Hu, Chun-Li; Mao, Fei-Fei; Feng, Jiang-He; Mao, Jiang-Gao (2019-02-11). "A Facile Route to Nonlinear Optical Materials: Three-Site Aliovalent Substitution Involving One Cation and Two Anions". Angewandte Chemie. 131 (7): 2120–2124. doi:10.1002/ange.201813968. PMID 30589189.
  7. Abudouwufu, Tushagu; Zhang, Min; Cheng, Shichao; Yang, Zhihua; Pan, Shilie (2019-01-24). "Ce(IO 3 ) 2 F 2 ⋅H 2 O: The First Rare-Earth-Metal Iodate Fluoride with Large Second Harmonic Generation Response". Chemistry - A European Journal. 25 (5): 1221–1226. doi:10.1002/chem.201804995. PMID 30408250.
  8. Wu, Chao; Lin, Lin; Jiang, Xingxing; Lin, Zheshuai; Huang, Zhipeng; Humphrey, Mark G.; Halasyamani, P. Shiv; Zhang, Chi (2019-12-24). "K 5 (W 3 O 9 F 4 )(IO 3 ): An Efficient Mid-Infrared Nonlinear Optical Compound with High Laser Damage Threshold". Chemistry of Materials. 31 (24): 10100–10108. doi:10.1021/acs.chemmater.9b03214. ISSN 0897-4756.
  9. Mao, Fei-Fei; Hu, Chun-Li; Xu, Xiang; Yan, Dong; Yang, Bing-Ping; Mao, Jiang-Gao (2017-02-13). "Bi(IO 3 )F 2 : The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect". Angewandte Chemie. 129 (8): 2183–2187. doi:10.1002/ange.201611770.
  10. Zhang, Min; Su, Xin; Mutailipu, Miriding; Yang, Zhihua; Pan, Shilie (2017-02-14). "Bi 3 OF 3 (IO 3 ) 4 : Metal Oxyiodate Fluoride Featuring a Carbon-Nanotube-like Topological Structure with Large Second Harmonic Generation Response". Chemistry of Materials. 29 (3): 945–949. doi:10.1021/acs.chemmater.6b05468. ISSN 0897-4756.
  11. Liu, Hongming; Wu, Qi; Jiang, Xingxing; Lin, Zheshuai; Meng, Xianggao; Chen, Xingguo; Qin, Jingui (2017-08-01). "ABi 2 (IO 3 ) 2 F 5 (A=K, Rb, and Cs): A Combination of Halide and Oxide Anionic Units To Create a Large Second-Harmonic Generation Response with a Wide Bandgap". Angewandte Chemie International Edition. 56 (32): 9492–9496. doi:10.1002/anie.201705672. PMID 28631860.
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