Laplace pressure

The Laplace pressure is the pressure difference between the inside and the outside of a curved surface that forms the boundary between a gas region and a liquid region.[1] The pressure difference is caused by the surface tension of the interface between liquid and gas.

The Laplace pressure is determined from the Young–Laplace equation given as[2]

${\displaystyle \Delta P\equiv P_{\text{inside}}-P_{\text{outside}}=\gamma \left({\frac {1}{R_{1}}}+{\frac {1}{R_{2}}}\right),}$

where ${\displaystyle R_{1}}$ and ${\displaystyle R_{2}}$ are the principal radii of curvature and ${\displaystyle \gamma }$ (also denoted as ${\displaystyle \sigma }$) is the surface tension. Although signs for these values vary, sign convention usually dictates positive curvature when convex and negative when concave.

The Laplace pressure is commonly used to determine the pressure difference in spherical shapes such as bubbles or droplets. In this case, ${\displaystyle R_{1}}$ = ${\displaystyle R_{2}}$:

${\displaystyle \Delta P=\gamma {\frac {2}{R}}}$

For a gas bubble within a liquid, there is only one surface. For a gas bubble with a liquid wall, beyond which is again gas, there are two surfaces, each contributing to the total pressure difference. If the bubble is spherical and the outer radius differs from the inner radius by a small distance, ${\displaystyle R_{o}=R_{i}+d}$, we find

${\displaystyle \Delta P=\Delta P_{i}+\Delta P_{o}=2\gamma \left({\frac {1}{R_{i}}}+{\frac {1}{R_{i}+d}}\right)={\frac {2\gamma }{R_{i}}}\left(1+{\frac {R_{i}}{R_{i}+d}}\right)={\frac {2\gamma }{R_{i}}}\left(1+{\frac {R_{i}+d}{R_{i}+d}}-{\frac {d}{R_{i}+d}}\right)={\frac {4\gamma }{R_{i}}}\left(1-{\frac {1}{2}}{\frac {d}{R_{i}+d}}\right)\approx {\frac {4\gamma }{R_{i}}}+{\mathcal {O}}(d).}$

Examples

A common example of use is finding the pressure inside an air bubble in pure water, where ${\displaystyle \gamma }$ = 72 mN/m at 25 °C (298 K). The extra pressure inside the bubble is given here for three bubble sizes:

Bubble diameter (2r) (μm)	${\displaystyle \Delta P}$ (Pa)	${\displaystyle \Delta P}$ (atm)
1000	288	0.00284
3.0	96000	0.947
0.3	960000	9.474

A 1 mm bubble has negligible extra pressure. Yet when the diameter is ~3 μm, the bubble has an extra atmosphere inside than outside. When the bubble is only several hundred nanometers, the pressure inside can be several atmospheres. One should bear in mind that the surface tension in the numerator can be much smaller in the presence of surfactants or contaminants. The same calculation can be done for small oil droplets in water, where even in the presence of surfactants and a fairly low interfacial tension ${\displaystyle \gamma }$ = 5–10 mN/m, the pressure inside 100 nm diameter droplets can reach several atmospheres. [3]

See also

• Ostwald ripening
• Kelvin equation
• Laplace number

References

1. Butt, Hans-Jürgen; Graf, Karlheinz; Kappl, Michael (2006). "Physics and Chemistry of Interfaces": 9. Cite journal requires |journal= (help)
2. Gennes, Pierre-Gilles de; Francoise Brochard-Wyart; David Quere (2004). Capillarity and Wetting Phenomena. Springer. pp. 7–8. ISBN 978-0-387-00592-8.
3. "Archived copy". Archived from the original on 2010-04-17. Retrieved 2010-04-03.CS1 maint: archived copy as title (link)