Selenide iodide

The selenide iodides are chemical compounds that contain both selenide ions (Se²⁻) and iodide ions (I⁻) and one or metal atoms. They are in the class of mixed anion compounds or chalcogenide halides.[1]

Some related compounds do not actually contain a selenide ion, instead containing an iodoselenium cation. These cations include SeI₃⁺, Se₂I₄²⁺, Se₆I₂²⁺, and polymeric Se₆I⁺.[2]

List

name	formula	MW	system	space group	unit cell	cell volume	density	properties	ref
	Ti₄Se₉I₆		triclinic	P1	a = 7.965 b = 10.339 c = 15.692; α = 79.116°, β = 75.861°, γ = 71.437°; Z = 2			black	[3]
α	AsSeI		monoclinic	P2_s	a=8.855 b=4.194 c=10.341 β=93.74 Z=4		5.14	melt 221 °C dark red metallic	[4]
β	AsSeI		cubic	F4₁32	a=11.05 Z=16		5.53	dark red metallic	[4]
	CuSe₃I		trigonal	R3m	a=9.601 V= 872.859				[5]
	AsF₆Se₆I								[2]
tribarium tetraselenide diiodide	Ba₃Se₄I₂		monoclinic	C2/c	a = 15.080 Å, b = 10.400 Å, c = 8.383 Å, β = 103.206°, Z = 4				[6]
	Cs₃Mo₆I₆Se₂I₆								[1]
	Cs₃Mo₆I₇SeI₆								[1]
	[Mo₃Se₇(TeI₃)I₂]I	1729.54		P2₃/n	a=10.4969 b=13.029 c=16.567 β =102.921° Z=4	2208.3	5.202		[1][7]
indium selenide iodide	InSeI		tetragonal	I4₁/a					[1]
heptasilver(I) tetraseleniogermanate(IV) selenide iodide	Ag₇GeISe₅		cubic	F43m	a=10.9864 Z=4	1326.1	6.740	black; silver ion conductor	[8]
Antimony selenide iodide	SbSeI		orthorhombic	Pnma				band gap 1.70 eV n-type semiconductor	[1]
	SbF₆Se₆I								[2]
	In₂Bi₃Se₇I								[1]
	InBi₂Se₄I								[1]
	CdBiSe₂I		monoclinic	C2/m					[1]
triniobium selenide heptaiodide	Nb₃SeI₇		hexagonal	P6₃mc					[1]
	Pd₂SeI₃		orthorhombic					metallic black	[9]
	Ta₂Se₈I		tetragonal		a = 9.59 c = 12.64			Charge-density-wave Weyl semimetal	[10][11]
tritantalum selenide heptaiodide	Ta₃SeI₇		hexagonal	P6₃mc					[1]
	Ta₄Se₉I₈								[1]
	WCl₆Se₆I								[2]
	Hg₃Se₂I₂		orthorhombic	Imma	a= 9.7660 b=19.381 c=9.6332 Z=8			light red	[1][12]
trimercury arsenic tetraselenide iodide	Hg₃AsSe₄I	1119.43	hexagonal	P6₃mc	a = 7.6902 c = 9.968 Z = 2	510.50	7.283	dark red	[13]
	Tl₆SeI₄		tetragonal	P4/mnc			7.4	band-gap 1.6 eV; semiconductor; melt 432 °C	[1][14]
Bismuth selenide iodide	BiSeI	414.84	orthorhombic	Pnma	a = 8.697 b = 4.2205 c = 10.574	388.1	7.100	band gap 1.3 eV; silver	[1][15]
	Bi₂CuSe₃I								[1]

References

Xiao, Jin-Rong; Yang, Si-Han; Feng, Fang; Xue, Huai-Guo; Guo, Sheng-Ping (September 2017). "A review of the structural chemistry and physical properties of metal chalcogenide halides". Coordination Chemistry Reviews. 347: 23–47. doi:10.1016/j.ccr.2017.06.010.
Beck, Johannes (1994-02-01). "New Forms and Functions of Tellurium: From Polycations to Metal Halide Tellurides". Angewandte Chemie International Edition in English. 33 (2): 163–172. doi:10.1002/anie.199401631. ISSN 0570-0833.
Poltarak, Pavel A.; Komarov, Vladislav Yu.; Kozlova, Svetlana G.; Sukhikh, Aleksandr S.; Artemkina, Sofya B.; Fedorov, Vladimir E. (March 2019). "First titanium square fragment {Ti4(μ4-Se)(μ2-Se2)4} in its selenoiodide: Synthesis and structure of Ti4Se9I6". Inorganica Chimica Acta. 488: 285–291. doi:10.1016/j.ica.2019.01.037.
Kniep, Rüdiger; Reski, Horst Dieter (February 1981). "Chalcogenide Iodides of Arsenic". Angewandte Chemie International Edition in English. 20 (2): 212–214. doi:10.1002/anie.198102121. ISSN 0570-0833.
Persson, Kristin (2014), Materials Data on CuSe3I (SG:166) by Materials Project, LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States), doi:10.17188/1203840, retrieved 2020-05-30
Wang, Jian; Lee, Kathleen; Kovnir, Kirill (2016). "Synthesis, crystal and electronic structure, and optical properties of two new chalcogenide-iodides: Ba3Q4I2 (Q = S, Se)". Inorganic Chemistry Frontiers. 3 (2): 306–312. doi:10.1039/C5QI00225G.
Sokolov, Maxim N.; Gushchin, Artem L.; Abramov, Pavel A.; Virovets, Alexander V.; Peresypkina, Eugenia V.; Fedin, Vladimir P. (May 2007). "Synthesis and Structures of Mo 3 Se 7 Te 2 Br 10 , Mo 3 Se 7 TeI 6 , and Mo 6 Te 21 I 22 Containing TeX 3 - (X = Br, I) Ligands Coordinated to a Triangular Cluster Core †". Inorganic Chemistry. 46 (11): 4677–4682. doi:10.1021/ic0700553. ISSN 0020-1669. PMID 17465541.
Aldon, L.; Belin, R.; Pontillon, Y. (2001-01-01). "Refinement of the crystal structure of heptasilver(I) tetraseleniogermanate(IV) selenide iodide, Ag7GeISe5". Zeitschrift für Kristallographie - New Crystal Structures. 216 (1–4): 191–192. doi:10.1524/ncrs.2001.216.14.191. ISSN 2197-4578. S2CID 98367111.
Thiele, Gerhard; Köhler-Degner, Maria; Wittmann, Kurt; Zoubek, Gerd (November 1978). "PdTeI and Pd2SeI3 - The First Chalcogenide Halides of a Platinum Metal". Angewandte Chemie International Edition in English. 17 (11): 852–853. doi:10.1002/anie.197808521. ISSN 0570-0833.
Gooth, J.; Bradlyn, B.; Honnali, S.; Schindler, C.; Kumar, N.; Noky, J.; Qi, Y.; Shekhar, C.; Sun, Y.; Wang, Z.; Bernevig, B. A. (November 2019). "Axionic charge-density wave in the Weyl semimetal (TaSe4)2I". Nature. 575 (7782): 315–319. arXiv:1906.04510. Bibcode:2019Natur.575..315G. doi:10.1038/s41586-019-1630-4. ISSN 0028-0836. PMID 31590178. S2CID 184487056.
Shi, Wujun; Wieder, Benjamin J.; Meyerheim, H. L.; Sun, Yan; Zhang, Yang; Li, Yiwei; Shen, Lei; Qi, Yanpeng; Yang, Lexian; Jena, Jagannath; Werner, Peter (2019-09-11). "A Charge-Density-Wave Weyl Semimetal". arXiv:1909.04037 [cond-mat.mtrl-sci].
Beck, Johannes; Hedderich, Sylvia (April 2000). "Synthesis and Crystal Structure of Hg3S2I2 and Hg3Se2I2, New Members of the Hg3E2X2 Family". Journal of Solid State Chemistry. 151 (1): 73–76. Bibcode:2000JSSCh.151...73B. doi:10.1006/jssc.1999.8624.
Beck, Johannes; Hedderich, Sylvia; Köllisch, Klaus (December 2000). "Hg 3 AsE 4 X (E = S, Se; X = Cl, Br, I), a Family of Isotypic Compounds with an Acentric, Layered Structure". Inorganic Chemistry. 39 (25): 5847–5850. doi:10.1021/ic0003527. ISSN 0020-1669. PMID 11151388.
Owens, Alan (2016-04-19). Compound Semiconductor Radiation Detectors. Taylor & Francis. pp. 339–340. ISBN 978-1-4398-7313-7.
Braun, Thomas P.; DiSalvo, Francis J. (2000-01-15). "Bismuth selenide iodide". Acta Crystallographica Section C Crystal Structure Communications. 56 (1): e1–e2. doi:10.1107/S0108270199016017. ISSN 0108-2701.

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[mch-1] Xiao, Jin-Rong; Yang, Si-Han; Feng, Fang; Xue, Huai-Guo; Guo, Sheng-Ping (September 2017). "A review of the structural chemistry and physical properties of metal chalcogenide halides". Coordination Chemistry Reviews. 347: 23–47. doi:10.1016/j.ccr.2017.06.010.

[:1-2] Beck, Johannes (1994-02-01). "New Forms and Functions of Tellurium: From Polycations to Metal Halide Tellurides". Angewandte Chemie International Edition in English. 33 (2): 163–172. doi:10.1002/anie.199401631. ISSN 0570-0833.

[3] Poltarak, Pavel A.; Komarov, Vladislav Yu.; Kozlova, Svetlana G.; Sukhikh, Aleksandr S.; Artemkina, Sofya B.; Fedorov, Vladimir E. (March 2019). "First titanium square fragment {Ti4(μ4-Se)(μ2-Se2)4} in its selenoiodide: Synthesis and structure of Ti4Se9I6". Inorganica Chimica Acta. 488: 285–291. doi:10.1016/j.ica.2019.01.037.

[:0-4] Kniep, Rüdiger; Reski, Horst Dieter (February 1981). "Chalcogenide Iodides of Arsenic". Angewandte Chemie International Edition in English. 20 (2): 212–214. doi:10.1002/anie.198102121. ISSN 0570-0833.

[5] Persson, Kristin (2014), Materials Data on CuSe3I (SG:166) by Materials Project, LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States), doi:10.17188/1203840, retrieved 2020-05-30

[6] Wang, Jian; Lee, Kathleen; Kovnir, Kirill (2016). "Synthesis, crystal and electronic structure, and optical properties of two new chalcogenide-iodides: Ba3Q4I2 (Q = S, Se)". Inorganic Chemistry Frontiers. 3 (2): 306–312. doi:10.1039/C5QI00225G.

[7] Sokolov, Maxim N.; Gushchin, Artem L.; Abramov, Pavel A.; Virovets, Alexander V.; Peresypkina, Eugenia V.; Fedin, Vladimir P. (May 2007). "Synthesis and Structures of Mo 3 Se 7 Te 2 Br 10 , Mo 3 Se 7 TeI 6 , and Mo 6 Te 21 I 22 Containing TeX 3 - (X = Br, I) Ligands Coordinated to a Triangular Cluster Core †". Inorganic Chemistry. 46 (11): 4677–4682. doi:10.1021/ic0700553. ISSN 0020-1669. PMID 17465541.

[8] Aldon, L.; Belin, R.; Pontillon, Y. (2001-01-01). "Refinement of the crystal structure of heptasilver(I) tetraseleniogermanate(IV) selenide iodide, Ag7GeISe5". Zeitschrift für Kristallographie - New Crystal Structures. 216 (1–4): 191–192. doi:10.1524/ncrs.2001.216.14.191. ISSN 2197-4578. S2CID 98367111.

[9] Thiele, Gerhard; Köhler-Degner, Maria; Wittmann, Kurt; Zoubek, Gerd (November 1978). "PdTeI and Pd2SeI3 - The First Chalcogenide Halides of a Platinum Metal". Angewandte Chemie International Edition in English. 17 (11): 852–853. doi:10.1002/anie.197808521. ISSN 0570-0833.

[10] Gooth, J.; Bradlyn, B.; Honnali, S.; Schindler, C.; Kumar, N.; Noky, J.; Qi, Y.; Shekhar, C.; Sun, Y.; Wang, Z.; Bernevig, B. A. (November 2019). "Axionic charge-density wave in the Weyl semimetal (TaSe4)2I". Nature. 575 (7782): 315–319. arXiv:1906.04510. Bibcode:2019Natur.575..315G. doi:10.1038/s41586-019-1630-4. ISSN 0028-0836. PMID 31590178. S2CID 184487056.

[11] Shi, Wujun; Wieder, Benjamin J.; Meyerheim, H. L.; Sun, Yan; Zhang, Yang; Li, Yiwei; Shen, Lei; Qi, Yanpeng; Yang, Lexian; Jena, Jagannath; Werner, Peter (2019-09-11). "A Charge-Density-Wave Weyl Semimetal". arXiv:1909.04037 [cond-mat.mtrl-sci].

[12] Beck, Johannes; Hedderich, Sylvia (April 2000). "Synthesis and Crystal Structure of Hg3S2I2 and Hg3Se2I2, New Members of the Hg3E2X2 Family". Journal of Solid State Chemistry. 151 (1): 73–76. Bibcode:2000JSSCh.151...73B. doi:10.1006/jssc.1999.8624.

[13] Beck, Johannes; Hedderich, Sylvia; Köllisch, Klaus (December 2000). "Hg 3 AsE 4 X (E = S, Se; X = Cl, Br, I), a Family of Isotypic Compounds with an Acentric, Layered Structure". Inorganic Chemistry. 39 (25): 5847–5850. doi:10.1021/ic0003527. ISSN 0020-1669. PMID 11151388.

[14] Owens, Alan (2016-04-19). Compound Semiconductor Radiation Detectors. Taylor & Francis. pp. 339–340. ISBN 978-1-4398-7313-7.

[15] Braun, Thomas P.; DiSalvo, Francis J. (2000-01-15). "Bismuth selenide iodide". Acta Crystallographica Section C Crystal Structure Communications. 56 (1): e1–e2. doi:10.1107/S0108270199016017. ISSN 0108-2701.