Chloramination

Chloramination is the treatment of drinking water with a chloramine disinfectant.[1] Both chlorine and small amounts of ammonia are added to the water one at a time which react together to form chloramine (also called combined chlorine), a long lasting disinfectant. Chloramine disinfection is used in both small and large water treatment plants.

Use

In the United States, the maintenance of what is called a "residual" of disinfectant that stays in the water distribution system while it is delivered to people's homes is required by the Environmental Protection Agency (EPA).

The EPA regulations give two choices for disinfectant residual — chlorine or chloramine. Many major water agencies are changing to chloramine to better meet current and anticipated federal drinking water regulations and to protect the public health.

Chlorine versus chloramine

There are many similarities between chlorine and chloramine. Both provide effective residual disinfection with minimal risk to public health. Both are toxic to fish and amphibians. Both chlorine and chloramine react with other compounds in the water to form what are called "disinfection byproducts".

The difference is that chlorine forms many byproducts, including trihalomethanes (THM) and haloacetic acids (HAA), whereas chloramine forms a significantly lower amount of THMs and HAAs but also forms N-nitrosodimethylamine (NDMA) a highly toxic chemical. One of the principal benefits of chloramine is that its use reduces the overall levels of these regulated contaminants compared to chlorine.

Adverse effects

Chloramine is toxic to fish and amphibians. Chloramine, like chlorine, comes in direct contact with their bloodstream through fish gills and must be removed from water added to aquariums and fish ponds. It must also be removed from water prior to use in dialysis machines, since water comes into direct contact with the bloodstream during treatment. Since the 1980s, most dialysis machines are built with filters to remove chloramines.[2]

Chloramine is generally considered a problem in brewing beer; like chlorine it can react with and change some of the natural plant flavors that make up the beer, and it may slow or alter the yeast. Because chloramine dissipates much more slowly than chlorine from water, beer-makers prefer carbon filtration and / or Campden tablets to neutralize it in the water.[3]

People have no trouble digesting chlorine or chloramine at the levels found in public drinking water; this water is not introduced directly into the human bloodstream. In the United States, the United States Environmental Protection Agency set minimum and maximum health-based safe levels for chloramine in drinking water.[4] Elsewhere, similar oversight agencies may set drinking water quality standards for chloramine.

Two home builders filed lawsuits against Moulton Niguel Water District in 2012, (in Orange County CA), arguing that pinhole leaks in copper water piping in their homes was due to faulty water treatment with chloramine. Pinhole leaks cause expensive damage to people's homes, and the builders claim that they must repipe houses at great expense to deal with the problem. Officials observed that only the two builders have filed suit, but as of late 2013 the number of lawsuits had expanded.[5][6]

Nitrogenous disinfection by-products are liable to convert to nitrosamines by the action of chlorination and chloramination. Other NDBPs include halonitroalkanes, halonitriles, and haloamides.[7]

Removing monochloramine from water

Chloramines should be removed from water for dialysis, aquariums, hydroponic applications, and homebrewing beer.. Chloramine must be removed from water prior to use in kidney dialysis machines because it can cause hemolytic anemia if it enters the blood stream.[8] In hydroponic applications, chloramine stunts the growth of plants.[9]

When a chemical or biological process that changes the chemistry of chloramines is used, it falls under reductive dechlorination. Other techniques use physical—not chemical—methods for removing chloramines.

Ultraviolet light

The use of ultraviolet light for chlorine or chloramine removal is an established technology that has been widely accepted in pharmaceutical, beverage, and dialysis applications.[10] UV is also used for disinfection at aquatic facilities.[11]

Ascorbic acid and sodium ascorbate

Ascorbic acid (vitamin C) and sodium ascorbate completely neutralize both chlorine and chloramine, but degrade in a day or two, which makes them usable only for short-term applications. SFPUC determined that 1000 mg of vitaminC  tablets, crushed and mixed in with bath water, completely remove chloramine in a medium-size bathtub without significantly depressing pH.[12]

Activated carbon

Activated carbon has been used for chloramine removal long before catalytic carbon, a form of activated carbon, became available; standard activated carbon requires a very long contact time, which means a large volume of carbon is needed. For thorough removal, up to four times the contact time of catalytic carbon may be required.

Most dialysis units now depend on granular activated carbon (GAC) filters, two of which should be placed in series so that chloramine breakthrough can be detected after the first one, before the second one fails.[13] Additionally, sodium metabisulfite injection may be used in certain circumstances.[14]

Campden tablets

Home brewers use reducing agents such as sodium metabisulfite or potassium metabisulfite (both proprietary sold as Campden tablets) to remove chloramine from brewing fermented beverages. However, residual sulfite can cause off flavors in beer[15] so potassium metabisulfite is preferred.

Sodium thiosulfate

Sodium thiosulfate is used to dechlorinate tapwater for aquariums or treat effluent from wastewater treatments prior to release into rivers. The reduction reaction is analogous to the iodine reduction reaction. Treatment of tapwater requires between 0.1 and 0.3 grams of pentahydrated (crystalline) sodium thiosulfate per 10 L of water. Many animals are sensitive to chloramine, and it must be removed from water given to many animals in zoos.

Other methods

Chloramine, like chlorine, can be removed by boiling and aging. However, time required to remove chloramine is much longer than that of chlorine. The time required to remove half of the chloramine (half-life) from 10 US gallons (38 l; 8.3 imp gal) of water by boiling is 26.6 minutes, whereas the half-life of free chlorine in boiling 10 gallons of water is only 1.8 minutes.[16] Aging may take weeks to remove chloramines, whereas chlorine disappears in a few days.[17][18]

References
  1. Chloramines Archived 2010-06-20 at the Wayback Machine, Water Quality Association
  2. Ward, D. M. (Oct 1996). "Chloramine removal from water used in hemodialysis". Adv Ren Replace Ther. 3 (4): 337–47. doi:10.1016/s1073-4449(96)80014-8. PMID 8914698.
  3. http://morebeer.com/articles/removing_chloramines_from_water
  4. http://water.epa.gov/drink/contaminants/basicinformation/disinfectants.cfm EPA basic information about chloramines
  5. http://www.ocregister.com/articles/water-340682-leaks-copper.html, "Archived copy" (PDF). Archived from the original (PDF) on 2014-07-29. Retrieved 2012-10-25.CS1 maint: archived copy as title (link)
  6. "Archived copy". Archived from the original on 2014-05-22. Retrieved 2014-06-23.CS1 maint: archived copy as title (link)
  7. Shah, Amisha D.; Mitch, William A. (2012). "Halonitroalkanes, Halonitriles, Haloamides, and N-Nitrosamines: A Critical Review of Nitrogenous Disinfection Byproduct Formation Pathways". Environmental Science & Technology. 46 (1): 119–131. Bibcode:2012EnST...46..119S. doi:10.1021/es203312s. PMID 22112205.
  8. Hakim, Nadey (2009). Artificial Organs. London: Springer-Verlag. p. 51. ISBN 9781848822818. Retrieved 2014-06-14. Water that contains chloramine is safe for people to drink, bathe, and cook in because the digestive process neutralizes it. Chloramine can, however, easily harm patients if it enters the blood stream during the dialysis process causing hemolytic anemia.
  9. Date, S.; Terabayashi, S.; Kobayashi, Y.; Fujime, Y. (2005), "Effects of chloramines concentration in nutrient solution and exposure time on plant growth in hydroponically cultured lettuce", Scientia Horticulturae, 103 (3): 257–265, doi:10.1016/j.scienta.2004.06.019
  10. Adelstein, Ben (2010-10-13). "Considering UV technology in water bottling". Watertechonline.com. Archived from the original on 2013-02-09. Retrieved 2013-11-23.
  11. "dechloraminator". UVgermi.com. 2017-08-30.
  12. "Questions Regarding Chlorine and Chloramine Removal From Water (Updated June 2013)". San Francisco Public Utilities Commission. Retrieved 2013-11-23.
  13. Ward, D. M. (Oct 1996). "Chloramine removal from water used in hemodialysis". Adv. Ren. Replace Ther. 3 (4): 337–347. doi:10.1016/S1073-4449(96)80014-8. PMID 8914698.
  14. Handbook of Dialysis, page 81
  15. Michael J. Lewis; Tom W. Young (31 October 2002). Brewing. Springer Science & Business Media. ISBN 978-0-306-47274-9.
  16. "Experiments in Removing Chlorine and Chloramine From Brewing Water" (PDF). 1998-11-03. Archived from the original (PDF) on 2013-11-10. Retrieved 2013-11-23.
  17. "Chloramination City of St. Petersburg". www.stpete.org. Retrieved 2020-01-18.
  18. "Chloramine Conversion | City of Richmond". www.richmondtx.gov. Retrieved 2020-01-18.
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