Neodymium fluoride
Neodymium(III) fluoride is an inorganic chemical compound of neodymium and fluorine with the formula NdF3. It is a purplish pink colored solid with a high melting point. Like other lanthanide fluorides it is highly insoluble in water which allows it to be synthesised from aqueous neodymium nitrate via a reaction with hydrofluoric acid, from which it precipitates as a hydrate:[1]
- Nd(NO3)3(aq) + 3 HF → NdF3•½H2O + 3 HNO3
Names | |
---|---|
Other names
Neodymium trifluoride | |
Identifiers | |
3D model (JSmol) |
|
ChemSpider | |
ECHA InfoCard | 100.033.852 |
EC Number |
|
PubChem CID |
|
CompTox Dashboard (EPA) |
|
| |
| |
Properties | |
NdF3 | |
Molar mass | 201.24 g/mol |
Appearance | vibrant pink/violet solid |
Density | 6.5g/cm3 |
Melting point | 1,374 °C (2,505 °F; 1,647 K) |
Structure | |
Tricapped trigonal prismatic (nine-coordinate) | |
Hazards | |
GHS pictograms | |
GHS Signal word | Warning |
H302, H312, H315, H319, H332, H335 | |
P261, P264, P270, P271, P280, P301+312, P302+352, P304+312, P304+340, P305+351+338, P312, P321, P322, P330, P332+313, P337+313, P362, P363, P403+233, P405, P501 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
Infobox references | |
Anhydrous material may be obtained by the simple drying of the hydrate, in contrast to the hydrates of other neodymium halides, which form mixed oxyhalides if heated.[1]
References
- Greenwood, N. N.; Earnshaw, A. (1997). Chemistry of the elements (2nd ed.). Butterworth-Heinemann. p. 1240. ISBN 0-7506-3365-4.
This article is issued from Wikipedia. The text is licensed under Creative Commons - Attribution - Sharealike. Additional terms may apply for the media files.