Zanazziite

Zanazziite
	Brown crystallized zanazziite on the matrix
General
Category	Phosphate minerals
Formula; (repeating unit)	Ca2(Mg,Fe)(Mg,Fe,Mn,Al)4Be4(OH)4(PO4)6·6H2O
Strunz classification	8.DA.10
Crystal system	Monoclinic
Crystal class	Prismatic (2/m) ; (same H-M symbol)
Space group	C2/c
Identification
Formula mass	1,044.11 g/mol
Color	Pale to dark olive green
Crystal habit	Bladed, columnar, prismatic
Cleavage	Good on [100], distinct on [010]
Fracture	Brittle
Mohs scale hardness	5
Luster	Vitreous – pearly
Streak	White
Diaphaneity	Transparent to translucent
Specific gravity	2.76
Optical properties	Biaxial (+)
Refractive index	nα = 1.606(2) nβ = 1.610 nγ = 1.620
Dispersion	r < v
Ultraviolet fluorescence	None
References	[1][2]

Zanazziite is a complex hydrated phosphate mineral from the roscherite group. It is a magnesium beryllium phosphate mineral.[3] Zanazziite arises as barrel-shaped crystals and can reach up to 4 mm. It grows alongside quartz minerals.[4] It is found in the crevices of Lavra da Ilha pegmatite, near Taquaral, in northeastern Minas Gerais, Brazil.[4] Zanazziite is named after Pier F. Zanazzi. Zanazziite has an ideal chemical formula of Ca₂Mg₅Be₄(PO₄)₆(OH)₄·6H₂O.[4]

Composition

Zanazzite was recently analyzed with an ARL-SEMQ microprobe; the values were Durango apatite for P, Rockport fayalite for Mn, and Kakanui hornblende for all others.[4] In a separate sample, Beryllium was 84.93 mg by atomic absorption spectrophotometry. To determine water an H analyzer was used on duplicate samples of about 25 mg. FeO was determined by titration. The spectroscopic analysis and other microprobes revealed P₂O₅, 39.27, SiO₂ 0.36, Al₂O₃ 1.54, Fe₂O₃ 0.76, CaO 10.65, MgO 11.66, FeO 9.63, MnO 1.77, BeO 9.81, H
2O 13.32, total of 98.77.[4][5] Zanazziite belongs to the roscherite-group. The roscherite-group nomenclature is based on the dominant cation in the Me-site; valid species include: Roscherite ( ${\ce {Mn^2+}}$ ), Zanazziite ( ${\ce {Mg^2+}}$ ) and Greifensteinite ( ${\ce {Fe^2+}}$ ).[4] The chemical relationship among all of the minerals in the roscherite group rely on a common formula (roscherite) Ca₂Mn₅Be₄(PO₄)₆(OH)₄·6H₂O, in which the Mn site can be occupied by other cations previously mentioned.[6]

Structure

Zanazzite belongs to the monoclinic space group C2/c. X-ray diffraction showed the strongest lines in Å, with intensities and indices: 9.50 (90) (110), 5.91 (100) (020), 3.16 (70) (330), 3.05 (50) (510), 2.766 (50) (240), 2.682 (40b) (600), 2.208 (40), 1.642 (50b).[4] X-ray diffraction analyzed cations sharing on octahedral sites. Uncertainty in analyzing zanazziites distribution of cations on M1 and M2 sites.[4] The M2 site in zanazziite is indistinct; it contains two Me-O bond distances, and two Me-OH bond distances.[5] The crystal structure and monoclinic symmetry of the cell data edge lengths: a=15.876A, b=11.860A, c=6.607A, and angle: beta=95.49 degrees. The axial ratio of zanazziite is a=1.3391 b=1 and c=0.5571.[6][7] The biaxial orientation of the extinction angles: $X=b;Z^{a}=3$ degrees, angles: $\alpha =1.606,\beta =1.610,\gamma =1.620$ , optical axis angle: 2V which was measured = 72 degrees and 2V which was calculated = 65 degrees.[4][6] In X-ray scattering and diffraction models the data presents an approximation of the number of electrons in each atomic site, giving 17.3 e- in the M2 site and 64.8 e- in the M1 site.[4][6][7]

The crystals in Zanazziite are prismatic to bladed, usually rough, barrel-shaped, with indices {100}, {110} and {001}. Cleavages are on {100} good, and {010} distinct.[4]

Physical properties

Zanazziite is usually pale green and occasionally dark green. It is a 5 on the Mohs hardness scale.[5] Optically biaxial +, ex = 1.606, 13 =1.610, "y = 1.620, 2V, = 72°(65° calc) X = b, Z:[100] 3° in obtuse 13; and the density = 2.76 measured, 2.77 calculated. Zanazziite has a vitreous luster, slightly pearly on the cleavage surfaces. Its cleavage is {100} good, {010} distinct. Zanazziite is nonfluorescent in longwave or shortwave ultraviolet light.[4] Zanazziite also shares many physical properties with roscherite.

Geologic occurrence

The roscherite analog zanazziite was found in Lavar da Ilha deposits in Minas Gerais, Brazil.[8] Zanazziite grows usually along the surface of quartz minerals. It occurs in pegmatite in beds of the Jequitinhonha river valley.[4] The pegmatite consists of a wall zone rich in feldspar and muscovite, and a quartz core.[4][5] The core margin has small pockets and crevices which contain quartz crystals and a number of phosphate minerals (on which the roscherite minerals accumulate).[4] This is special to quartz and phosphate due to the rich locality of Minas Gerais. Minas Gerais contains the world's most diverse concentration of complex granitic pegmatites. This region is responsible for the production of gem beryl, chrysoberyl, topaz, tourmaline, and kunzite.[3][9]

References

Zanazziite: Zanazziite on Mindat.org
Zanazziite on Webmineral
Atencio, D., Chukanov, N.V., Coutinho, J.M.V., Menezes Filho, L.A D., Dubinchuk, V.T. and Möckel, S.(2007) Ruifrancoite, a new Fe3+ -dominant monoclinic member of the roscherite group from Galilea, Minas Gerais, Brazil. The Canadian Mineralogist.,45, 1263–1273.
Leavens, P.B., White, J.S., and Nelen, J.A.(1990) Zanazziite a new mineral from Minas Gerais, Brazil. The Mineralogical record 21, 413–417.
Fanfani, L., Zanazzi, P.F., and Zanzari, A.R. (1977) The crystal structure of roscherite. Tschermaks Min. Petr.Mitt., 22, 266–277.
Rastsvetaeva, R.K., Chukanov, N.V., and Verin, I.A.(2005) Crystal structure of roscherite. Dok. Akad. Nauk. Russia, 403, 768–771.
Rastsvetaeva, R., Rozenberg, K., Chukanov, N., and Möckel, S.(2009) The crystal structure of an iron-rich variety of zanazziite belonging to heteropolyhedral framework roscherite-group beryllophosphates. MAIK Nauk, 54, 568–571.
Rastsvetaeva, R.K., Barinova, A.V., Chukanov, N.V., and Pietraszko, A.(2004) Crystal structure of a magnesium-rich triclinic analogue of greifensteinite. Dok. Akad. Nauk. Russia., 398, 492–497.
Atencio, D., Coutinho, J.M.V., and Menezes Filho, L.A.D.(2005) Roscherite group minerals from Brazil. Mineral records., 4, 1–16.

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[1] Zanazziite: Zanazziite on Mindat.org

[2] Zanazziite on Webmineral

[Atencio-3] Atencio, D., Chukanov, N.V., Coutinho, J.M.V., Menezes Filho, L.A D., Dubinchuk, V.T. and Möckel, S.(2007) Ruifrancoite, a new Fe3+ -dominant monoclinic member of the roscherite group from Galilea, Minas Gerais, Brazil. The Canadian Mineralogist.,45, 1263–1273.

[Leavens-4] Leavens, P.B., White, J.S., and Nelen, J.A.(1990) Zanazziite a new mineral from Minas Gerais, Brazil. The Mineralogical record 21, 413–417.

[Fanfani-5] Fanfani, L., Zanazzi, P.F., and Zanzari, A.R. (1977) The crystal structure of roscherite. Tschermaks Min. Petr.Mitt., 22, 266–277.

[Rast05-6] Rastsvetaeva, R.K., Chukanov, N.V., and Verin, I.A.(2005) Crystal structure of roscherite. Dok. Akad. Nauk. Russia, 403, 768–771.

[Rast09-7] Rastsvetaeva, R., Rozenberg, K., Chukanov, N., and Möckel, S.(2009) The crystal structure of an iron-rich variety of zanazziite belonging to heteropolyhedral framework roscherite-group beryllophosphates. MAIK Nauk, 54, 568–571.

[8] Rastsvetaeva, R.K., Barinova, A.V., Chukanov, N.V., and Pietraszko, A.(2004) Crystal structure of a magnesium-rich triclinic analogue of greifensteinite. Dok. Akad. Nauk. Russia., 398, 492–497.

[9] Atencio, D., Coutinho, J.M.V., and Menezes Filho, L.A.D.(2005) Roscherite group minerals from Brazil. Mineral records., 4, 1–16.