Boron monoxide
Boron monoxide (B2O) is a chemical compound of boron and oxygen. Two experimental studies have proposed existence of diamond-like[1] and graphite-like[2] B2O, as for boron nitride and carbon solids. However, a later, systematic, experimental study of boron oxide phase diagram suggests that B2O is unstable.[3] The instability of the graphite-like B2O phase was also predicted theoretically.[4]
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| IUPAC name
Boron(I) oxide | |
| Other names
diboron monoxide | |
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| Properties | |
| B2O | |
| Molar mass | 37.621 g/mol |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
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References
- Endo, T.; Sato, T.; Shimada, M. (1987). "High-pressure synthesis of B2O with diamond-like structure". Journal of Materials Science Letters. 6 (6): 683. doi:10.1007/BF01770925. S2CID 137691715.
- Hall, H. T.; Compton, L. A. (1965). "Group IV Analogs and High Pressure, High Temperature Synthesis of B2O" (PDF). Inorganic Chemistry. 4 (8): 1213. doi:10.1021/ic50030a027.
- Solozhenko, V. L.; Kurakevych, O. O.; Turkevich, V. Z.; Turkevich, D. V. (2008). "Phase Diagram of the B−B2O2 System at 5 GPa: Experimental and Theoretical Studies". Journal of Physical Chemistry B. 112 (21): 6683–7. doi:10.1021/jp800625s. PMID 18457447.
- Grumbach, M.; Sankey, O.; McMillan, P. (1995). "Properties of B2O: An unsymmetrical analog of carbon". Physical Review B. 52 (22): 15807–15811. Bibcode:1995PhRvB..5215807G. doi:10.1103/PhysRevB.52.15807. PMID 9980955.
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