Phenoxy herbicide

Phenoxy herbicides (or "phenoxies") are a family of chemicals related to the growth hormone indoleacetic acid (IAA). When sprayed on broad-leaf plants they induce rapid, uncontrolled growth ("growing to death"). When sprayed on monocotyledonous (grass) crops such as wheat or corn, they selectively kill broad-leaf weeds, leaving the crops relatively unaffected. The wide variety of phenoxies in use today can be grouped into the phenoxyacetic, phenoxybutyric and phenoxypropionic subtypes,[1] the latter containing the aryloxyphenoxypropionic subtype with the greatest number of commercial variants. Chemically, they are carboxylic acids, typically applied in an ester or salt form.

2,4-Dichlorophenoxyacetic acid, a phenoxy herbicide

First introduced in 1946, these herbicides were in widespread use in agriculture by the middle of the 1950s. The best known phenoxy herbicides are MCPA,[2] 2,4-dichlorophenoxyacetic acid (2,4-D) and 2,4,5-trichlorophenoxyacetic acid (2,4,5-T). 2,4,5-T was later found to be inherently contaminated with the dioxin 2,3,7,8-tetrachlorodibenzo-para-dioxin (TCDD), and has since been banned in most countries. 2,4-D may also contain dioxin impurities, depending on the production method.[3]

See also

References
  1. Samel, Ulf-Rainer; Kohler, Walter; Gamer, Armin Otto; Keuser, Ullrich (2005). "Propionic Acid and Derivatives". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a22_223.
  2. Western People Thistle and rush control in grassland15 Aug 2007
  3. 2,4-Dichlorophenoxyacetic acid (2,4-D) - Environmental Aspects


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