Mars surface color

The surface of the planet Mars appears reddish from a distance because of rusty dust suspended in the atmosphere.[1] From close up, it looks more of a butterscotch,[1] and other common surface colors include golden, brown, tan, and greenish, depending on minerals.[1]

Yogi Rock, analyzed by the Sojourner rover (July 4, 1997)

The apparent colour of the Martian surface enabled humans to distinguish it from other planets early in human history and motivated them to weave fables of war in association with Mars. One of its earliest recorded names, Har decher, literally meant "Red One" in Egyptian.[2] Its color may have also contributed to a malignant association in Indian astrology, as it was given the names Angaraka and Lohitanga, both reflecting the distinctively red color of Mars as seen by the naked eye.[2] Modern robotic explorers have shown that not only the surfaces, but also the skies above may appear red under sunlit conditions on Mars.

Reason for red and its extensiveness

Modern observations indicate that Mars's redness is skin deep. The Martian surface looks reddish primarily because of a ubiquitous dust layer (particles are typically between 3 μm to 45 μm across [3][4]) that is typically on the order of millimeters thick. Even where the thickest deposits of this reddish dust occur, such as the Tharsis area, the dust layer is probably not more than 2 m (7 feet) thick.[5] Therefore, the reddish dust is essentially an extremely thin veneer on the Martian surface and does not represent the bulk of the Martian subsurface in any way.

Curiosity's view of Martian soil and boulders after crossing the "Dingo Gap" sand dune (February 9, 2014; raw color).

Martian dust is reddish mostly due to the spectral properties of nanophase ferric oxides (npOx) that tend to dominate in the visible spectrum. The specific npOx minerals have not been fully constrained, but nanocrystalline red hematite (α-Fe2O3) may be the volumetrically dominant one,[6] at least at the less than 100 μm sampling depth[7] of infrared remote sensors such as the Mars Express OMEGA instrument. The rest of the iron in the dust, perhaps as much as 50% of the mass, may be in titanium enriched magnetite (Fe3O4).[8] Magnetite is usually black in colour with a black streak,[9] and does not contribute to the reddish hue of dust.

The mass fraction of chlorine and sulfur in the dust is greater than that which has been found (by the Mars Exploration Rovers Spirit and Opportunity) in the soil types at Gusev crater and Meridiani Planum. The sulfur in the dust also shows a positive correlation with npOx.[10] This suggests that very limited chemical alteration by thin brine films (facilitated by the formation of frost from atmospheric H2O) may be producing some of the npOx.[10] In addition, remote sensing observations of atmospheric dust (which shows slight compositional and grain size differences from surface dust), indicates that the bulk volume of dust grains consists of plagioclase feldspar and zeolite, along with minor pyroxene and olivine components.[11] Such fine material can be generated easily via mechanical erosion from feldspar-rich basalts, such as rocks in the southern highlands on Mars.[11] Collectively, these observations indicate that any chemical alteration of dust by aqueous activity has been very minor.

The occurrence of nanophase ferric oxides (npOx) in dust

There are several processes that can yield npOx as an oxidation product without the involvement of free oxygen (O2). One or more of those processes may have dominated on Mars, since atmospheric modeling over geologic time scales indicates that free O2 (generated mostly via the photodissociation of water (H2O))[12] may have always been a trace component with a partial pressure not exceeding 0.1 micropascal (μPa).[13]

Rock-strewn surface imaged by Mars Pathfinder (July 4, 1997)

One oxygen-(O2)-independent process involves a direct chemical reaction of ferrous iron (Fe2+) (commonly present in typical igneous minerals) or metallic iron (Fe) with water (H2O) to produce ferric iron (Fe3+(aq)), which typically leads to hydroxides such as goethite (FeO•OH)[12] under experimental conditions.[14] While this reaction with water (H2O) is thermodynamically disfavored, it may be sustained nevertheless, by the rapid loss of the molecular hydrogen (H2) byproduct.[13] The reaction can be further facilitated by dissolved carbon dioxide (CO2) and sulfur dioxide (SO2), which lower the pH of brine films increasing the concentration of the more oxidative hydrogen ions (H+).[14]

However, higher temperatures (c. 300 °C) are usually needed to decompose Fe3+ (oxy)hydroxides such as goethite into hematite. The formation of palagonitic tephra on the upper slopes of the Mauna Kea volcano may mirror such processes, as consistent with the intriguing spectral and magnetic similarities between palagonitic tephra and Martian dust.[15] In spite of the need for such kinetic conditions, prolonged arid and low pH conditions on Mars (such as diurnal brine films) may lead to the eventual transformation of goethite into hematite given the thermodynamic stability of the latter.[14]

Fe and Fe2+ may also be oxidized by the activity of hydrogen peroxide (H2O2). Even though the H2O2 abundance in the Martian atmosphere is very low,[13] it is temporally persistent and a much stronger oxidant than H2O. H2O2-driven oxidation to Fe3+ (usually as hydrated minerals), has been observed experimentally.[14] In addition, the pervasiveness of the α-Fe2O3 spectral signature, but not of hydrated Fe3+ minerals reinforces the possibility that npOx may form even without the thermodynamically disfavored intermediaries such as geothite.[6]

There is also evidence that hematite might form from magnetite in the course of erosion processes. Experiments at the Mars Simulation Laboratory of Aarhus University in Denmark show that when a mixture of magnetide powder, quartz sand, and quartz dust particles is tumbled in a flask, some of the magnetite converts to hematite, coloring the sample red. The proposed explanation for this effect is that when quartz is fructured by the grinding, certain chemical bonds get broken at the newly exposed surfaces; when these surfaces come in contact with magnetite, oxygen atoms may be transferred from quartz surface to magnetite, forming hematite.[16]

Red skies on Mars

Approximately true-colour in situ images from the Mars Pathfinder and Mars Exploration Rover missions indicate that the Martian sky may also appear reddish to humans. Absorption of sunlight in the 0.4-0.6 μm range by dust particles may be the primary reason for the redness of the sky.[17] An additional contribution may come from the dominance of photon scattering by dust particles at wavelengths in the order 3 μm,[4] which is in the near-infrared range, over Rayleigh scattering by gas molecules.[18]

References
  1. NASA - Mars in a Minute: Is Mars Really Red? (Transcript)
  2. Kieffer, Hugh H., Bruce M. Jakosky, and Conway W. Snyder (1992), "The planet Mars: From antiquity to the present," in Mars, University of Arizona Press, Tucson, AZ, p. 2 Archived 2011-06-04 at the Wayback Machine ISBN 0-8165-1257-4
  3. Fergason; et al. (11 February 2006). "Physical properties of the Mars Exploration Rover landing sites as inferred from Mini-TES–derived thermal inertia". Journal of Geophysical Research. 111 (E2): n/a. Bibcode:2006JGRE..111.2S21F. CiteSeerX 10.1.1.596.3226. doi:10.1029/2005JE002583.
  4. Lemmon; et al. (3 December 2004). "Atmospheric Imaging Results from the Mars Exploration Rovers: Spirit and Opportunity". Science. 306 (5702): 1753–1756. Bibcode:2004Sci...306.1753L. doi:10.1126/science.1104474. PMID 15576613.
  5. Ruff; Christensen (11 December 2002). "Bright and dark regions on Mars: Particle size and mineralogical characteristics based on Thermal Emission Spectrometer data". Journal of Geophysical Research. 107 (E12): 2–1–2–22. Bibcode:2002JGRE..107.5127R. doi:10.1029/2001JE001580.
  6. Bibring; et al. (21 April 2006). "Global Mineralogical and Aqueous Mars History Derived from OMEGA/Mars Express Data". Science. 312 (5772): 400–404. Bibcode:2006Sci...312..400B. doi:10.1126/science.1122659. PMID 16627738.
  7. Poulet; et al. (18 July 2007). "Martian surface mineralogy from Observatoire pour la Minéralogie, l'Eau, les Glaces et l'Activité on board the Mars Express spacecraft (OMEGA/MEx): Global mineral maps". Journal of Geophysical Research. 112 (E8): E08S02. Bibcode:2007JGRE..112.8S02P. doi:10.1029/2006JE002840. S2CID 16963908.
  8. Goetz; et al. The nature of Martian airborne dust. Indication of long-lasting dry periods on the surface of Mars (PDF). Seventh International Conference on Mars. Retrieved 2017-11-12.
  9. "Magnetite". mindat.org. Retrieved 2017-11-04.
  10. Yen; et al. (7 July 2005). "An integrated view of the chemistry and mineralogy of martian soils". Nature. 436 (7047): 49–54. Bibcode:2005Natur.436...49Y. doi:10.1038/nature03637. PMID 16001059.
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  14. Chevrier; et al. (15 August 2006). "Iron weathering products in a CO2 + (H2O or H2O2) atmosphere: Implications for weathering processes on the surface of Mars". Geochimica et Cosmochimica Acta. 70 (16): 4295–4317. Bibcode:2006GeCoA..70.4295C. doi:10.1016/j.gca.2006.06.1368.
  15. Morris; et al. (1 March 2001). "Phyllosilicate-poor palagonitic dust from Mauna Kea Volcano (Hawaii): A mineralogical analogue for magnetic Martian dust?". Journal of Geophysical Research. 106 (E3): 5057–5083. Bibcode:2001JGR...106.5057M. doi:10.1029/2000JE001328.
  16. Moskowitz, Clara (September 2009). "How Mars Turned Red: Surprising New Theory". Yahoo News. Archived from the original on September 25, 2009. Retrieved 2009-09-21.
  17. Bell III; et al. (28 September 2006). "Chromaticity of the Martian sky as observed by the Mars Exploration Rover Pancam instruments". Journal of Geophysical Research. 111 (E12): n/a. Bibcode:2006JGRE..11112S05B. doi:10.1029/2006JE002687.
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