Zinc titanate
Zinc titanate, also known as zinc titanium oxide, is an inorganic compound existing in three major forms: ZnTiO3 (ZnO-TiO2), Zn2TiO4 (2ZnO-TiO2) and Zn2Ti3O8 (2ZnO-3TiO2). It is used as a regenerable catalyst, a pigment and a sorbent of sulfur compounds at elevated temperatures.[1] It is a white powder that is insoluble in water.
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Other names
Zinc titanium oxide | |
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Properties | |
ZnTiO3 | |
Molar mass | 161.24 g/mol |
Appearance | White powder |
Insoluble | |
Hazards | |
Main hazards | Harmful (Xn) |
R-phrases (outdated) | R20 |
S-phrases (outdated) | S9, S36 |
NFPA 704 (fire diamond) | |
Flash point | None |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
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Synthesis and properties
The ZnTiO3, Zn2TiO4 and Zn2Ti3O8 forms crystallize in hexagonal, cubic (inverse spinel) and cubic structures, respectively. They can be produced by heating a mixture of ZnO and TiO2 powders or processing it with a ball mill.[1] Zn2Ti3O8 forms at lowest temperatures, followed by ZnTiO3 and then Zn2TiO4; the last phase dominates at temperatures above 1000 °C.[2]
Toxicity
Zinc titanate irritates the skin, mucous membranes and eyes. Zinc fumes can cause metal fume fever.[3]
References
- Klaus D. Sattler (1 May 2010). Nanotubes and Nanowires. CRC Press. pp. 13–. ISBN 978-1-4200-7542-7. Retrieved 10 March 2012.
- Aysel T. Atimtay; Douglas P. Harrison (1998). Desulfurization of hot coal gas. Springer. pp. 300–. ISBN 978-3-540-64726-3. Retrieved 10 March 2012.
- Material Safety Data Sheet. alfa.com