Isotopes of lutetium
Naturally occurring lutetium (71Lu) is composed of one stable isotope 175Lu (97.41% natural abundance) and one long-lived radioisotope, 176Lu with a half-life of 3.78 × 1010 years (2.59% natural abundance). Thirty-four radioisotopes have been characterized, with the most stable, besides 176Lu, being 174Lu with a half-life of 3.31 years, and 173Lu with a half-life of 1.37 years. All of the remaining radioactive isotopes have half-lives that are less than 9 days, and the majority of these have half-lives that are less than half an hour. This element also has 18 meta states, with the most stable being 177mLu (t1/2 160.4 days), 174mLu (t1/2 142 days) and 178mLu (t1/2 23.1 minutes).
| |||||||||||||||||||||||||||||||||
Standard atomic weight Ar, standard(Lu) |
| ||||||||||||||||||||||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
The isotopes of lutetium range in atomic weight from 149.973 (150Lu) to 183.961 (184Lu). The primary decay mode before the most abundant stable isotope, 175Lu, is electron capture (with some alpha and positron emission), and the primary mode after is beta emission. The primary decay products before 175Lu are isotopes of ytterbium and the primary products after are isotopes of hafnium.
List of isotopes
Nuclide [n 1] |
Z | N | Isotopic mass (Da) [n 2][n 3] |
Half-life [n 4][n 5] |
Decay mode [n 6] |
Daughter isotope [n 7] |
Spin and parity [n 8][n 5] |
Natural abundance (mole fraction) | |
---|---|---|---|---|---|---|---|---|---|
Excitation energy[n 5] | Normal proportion | Range of variation | |||||||
150Lu | 71 | 79 | 149.97323(54)# | 43(5) ms | p (80%) | 149Yb | (2+) | ||
β+ (20%) | 150Yb | ||||||||
150mLu | 34(15) keV | 80(60) μs [30(+95−15) μs] |
p | 149Yb | (1, 2) | ||||
151Lu | 71 | 80 | 150.96757682 | 80.6(5) ms | p (63.4%) | 150Yb | (11/2−) | ||
β+ (36.6%) | 151Yb | ||||||||
151mLu | 77(5) keV | 16(1) μs | p | 150Yb | (3/2+) | ||||
152Lu | 71 | 81 | 151.96412(21)# | 650(70) ms | β+ (85%) | 152Yb | (5−, 6−) | ||
β+, p (15%) | 151Tm | ||||||||
153Lu | 71 | 82 | 152.95877(22) | 0.9(2) s | α (70%) | 149Tm | 11/2− | ||
β+ (30%) | 153Yb | ||||||||
153m1Lu | 80(5) keV | 1# s | IT | 153Lu | 1/2+ | ||||
153m2Lu | 2502.5(4) keV | >0.1 μs | IT | 153Lu | 23/2− | ||||
153m3Lu | 2632.9(5) keV | 15(3) μs | IT | 153m2Lu | 27/2− | ||||
154Lu | 71 | 83 | 153.95752(22)# | 1# s | β+ | 154Yb | (2−) | ||
154m1Lu | 58(13) keV | 1.12(8) s | (9+) | ||||||
154m2Lu | >2562 keV | 35(3) μs | (17+) | ||||||
155Lu | 71 | 84 | 154.954316(22) | 68.6(16) ms | α (76%) | 151Tm | (11/2−) | ||
β+ (24%) | 155Yb | ||||||||
155m1Lu | 20(6) keV | 138(8) ms | α (88%) | 151Tm | (1/2+) | ||||
β+ (12%) | 155Yb | ||||||||
155m2Lu | 1781.0(20) keV | 2.70(3) ms | (25/2−) | ||||||
156Lu | 71 | 85 | 155.95303(8) | 494(12) ms | α (95%) | 152Tm | (2)− | ||
β+ (5%) | 156Yb | ||||||||
156mLu | 220(80)# keV | 198(2) ms | α (94%) | 152Tm | (9)+ | ||||
β+ (6%) | 156Yb | ||||||||
157Lu | 71 | 86 | 156.950098(20) | 6.8(18) s | β+ | 157Yb | (1/2+, 3/2+) | ||
α | 153Tm | ||||||||
157mLu | 21.0(20) keV | 4.79(12) s | β+ (94%) | 157Yb | (11/2−) | ||||
α (6%) | 153Tm | ||||||||
158Lu | 71 | 87 | 157.949313(16) | 10.6(3) s | β+ (99.09%) | 158Yb | 2− | ||
α (.91%) | 154Tm | ||||||||
159Lu | 71 | 88 | 158.94663(4) | 12.1(10) s | β+ (99.96%) | 159Yb | 1/2+# | ||
α (.04%) | 155Tm | ||||||||
159mLu | 100(80)# keV | 10# s | 11/2−# | ||||||
160Lu | 71 | 89 | 159.94603(6) | 36.1(3) s | β+ | 160Yb | 2−# | ||
α (10−4%) | 156Tm | ||||||||
160mLu | 0(100)# keV | 40(1) s | |||||||
161Lu | 71 | 90 | 160.94357(3) | 77(2) s | β+ | 161Yb | 1/2+ | ||
161mLu | 166(18) keV | 7.3(4) ms | IT | 161Lu | (9/2−) | ||||
162Lu | 71 | 91 | 161.94328(8) | 1.37(2) min | β+ | 162Yb | (1−) | ||
162m1Lu | 120(200)# keV | 1.5 min | β+ | 162Yb | 4−# | ||||
IT (rare) | 162Lu | ||||||||
162m2Lu | 300(200)# keV | 1.9 min | |||||||
163Lu | 71 | 92 | 162.94118(3) | 3.97(13) min | β+ | 163Yb | 1/2(+) | ||
164Lu | 71 | 93 | 163.94134(3) | 3.14(3) min | β+ | 164Yb | 1(−) | ||
165Lu | 71 | 94 | 164.939407(28) | 10.74(10) min | β+ | 165Yb | 1/2+ | ||
166Lu | 71 | 95 | 165.93986(3) | 2.65(10) min | β+ | 166Yb | (6−) | ||
166m1Lu | 34.37(5) keV | 1.41(10) min | EC (58%) | 166Yb | 3(−) | ||||
IT (42%) | 166Lu | ||||||||
166m2Lu | 42.9(5) keV | 2.12(10) min | 0(−) | ||||||
167Lu | 71 | 96 | 166.93827(3) | 51.5(10) min | β+ | 167Yb | 7/2+ | ||
167mLu | 0(30)# keV | >1 min | 1/2(−#) | ||||||
168Lu | 71 | 97 | 167.93874(5) | 5.5(1) min | β+ | 168Yb | (6−) | ||
168mLu | 180(110) keV | 6.7(4) min | β+ (95%) | 168Yb | 3+ | ||||
IT (5%) | 168Lu | ||||||||
169Lu | 71 | 98 | 168.937651(6) | 34.06(5) h | β+ | 169Yb | 7/2+ | ||
169mLu | 29.0(5) keV | 160(10) s | IT | 169Lu | 1/2− | ||||
170Lu | 71 | 99 | 169.938475(18) | 2.012(20) d | β+ | 170Yb | 0+ | ||
170mLu | 92.91(9) keV | 670(100) ms | IT | 170Lu | (4)− | ||||
171Lu | 71 | 100 | 170.9379131(30) | 8.24(3) d | β+ | 171Yb | 7/2+ | ||
171mLu | 71.13(8) keV | 79(2) s | IT | 171Lu | 1/2− | ||||
172Lu | 71 | 101 | 171.939086(3) | 6.70(3) d | β+ | 172Yb | 4− | ||
172m1Lu | 41.86(4) keV | 3.7(5) min | IT | 172Lu | 1− | ||||
172m2Lu | 65.79(4) keV | 0.332(20) μs | (1)+ | ||||||
172m3Lu | 109.41(10) keV | 440(12) μs | (1)+ | ||||||
172m4Lu | 213.57(17) keV | 150 ns | (6−) | ||||||
173Lu | 71 | 102 | 172.9389306(26) | 1.37(1) y | EC | 173Yb | 7/2+ | ||
173mLu | 123.672(13) keV | 74.2(10) μs | 5/2− | ||||||
174Lu | 71 | 103 | 173.9403375(26) | 3.31(5) y | β+ | 174Yb | (1)− | ||
174m1Lu | 170.83(5) keV | 142(2) d | IT (99.38%) | 174Lu | 6− | ||||
EC (.62%) | 174Yb | ||||||||
174m2Lu | 240.818(4) keV | 395(15) ns | (3+) | ||||||
174m3Lu | 365.183(6) keV | 145(3) ns | (4−) | ||||||
175Lu | 71 | 104 | 174.9407718(23) | Observationally Stable[n 9] | 7/2+ | 0.9741(2) | |||
175m1Lu | 1392.2(6) keV | 984(30) μs | (19/2+) | ||||||
175m2Lu | 353.48(13) keV | 1.49(7) μs | 5/2− | ||||||
176Lu[n 10][n 11] | 71 | 105 | 175.9426863(23) | 38.5(7)×109 y | β− | 176Hf | 7− | 0.0259(2) | |
176mLu | 122.855(6) keV | 3.664(19) h | β− (99.9%) | 176Hf | 1− | ||||
EC (.095%) | 176Yb | ||||||||
177Lu | 71 | 106 | 176.9437581(23) | 6.6475(20) d | β− | 177Hf | 7/2+ | ||
177m1Lu | 150.3967(10) keV | 130(3) ns | 9/2− | ||||||
177m2Lu | 569.7068(16) keV | 155(7) μs | 1/2+ | ||||||
177m3Lu | 970.1750(24) keV | 160.44(6) d | β− (78.3%) | 177Hf | 23/2− | ||||
IT (21.7%) | 177Lu | ||||||||
177m4Lu | 3900(10) keV | 7(2) min [6(+3−2) min] |
39/2− | ||||||
178Lu | 71 | 107 | 177.945955(3) | 28.4(2) min | β− | 178Hf | 1(+) | ||
178mLu | 123.8(26) keV | 23.1(3) min | β− | 178Hf | 9(−) | ||||
179Lu | 71 | 108 | 178.947327(6) | 4.59(6) h | β− | 179Hf | 7/2(+) | ||
179mLu | 592.4(4) keV | 3.1(9) ms | IT | 179Lu | 1/2(+) | ||||
180Lu | 71 | 109 | 179.94988(8) | 5.7(1) min | β− | 180Hf | 5+ | ||
180m1Lu | 13.9(3) keV | ~1 s | IT | 180Lu | 3− | ||||
180m2Lu | 624.0(5) keV | >=1 ms | (9−) | ||||||
181Lu | 71 | 110 | 180.95197(32)# | 3.5(3) min | β− | 181Hf | (7/2+) | ||
182Lu | 71 | 111 | 181.95504(21)# | 2.0(2) min | β− | 182Hf | (0,1,2) | ||
183Lu | 71 | 112 | 182.95757(32)# | 58(4) s | β− | 183Hf | (7/2+) | ||
184Lu | 71 | 113 | 183.96091(43)# | 20(3) s | β− | 184Hf | (3+) |
- mLu – Excited nuclear isomer.
- ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
- # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
- Bold half-life – nearly stable, half-life longer than age of universe.
- # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
-
Modes of decay:
EC: Electron capture IT: Isomeric transition p: Proton emission - Bold symbol as daughter – Daughter product is stable.
- ( ) spin value – Indicates spin with weak assignment arguments.
- Believed to undergo α decay to 171Tm
- primordial radionuclide
- Used in lutetium-hafnium dating
Lutetium-177
References
- Meija, Juris; et al. (2016). "Atomic weights of the elements 2013 (IUPAC Technical Report)". Pure and Applied Chemistry. 88 (3): 265–91. doi:10.1515/pac-2015-0305.
- Isotope masses from:
- Audi, Georges; Bersillon, Olivier; Blachot, Jean; Wapstra, Aaldert Hendrik (2003), "The NUBASE evaluation of nuclear and decay properties", Nuclear Physics A, 729: 3–128, Bibcode:2003NuPhA.729....3A, doi:10.1016/j.nuclphysa.2003.11.001
- Isotopic compositions and standard atomic masses from:
- de Laeter, John Robert; Böhlke, John Karl; De Bièvre, Paul; Hidaka, Hiroshi; Peiser, H. Steffen; Rosman, Kevin J. R.; Taylor, Philip D. P. (2003). "Atomic weights of the elements. Review 2000 (IUPAC Technical Report)". Pure and Applied Chemistry. 75 (6): 683–800. doi:10.1351/pac200375060683.
- Wieser, Michael E. (2006). "Atomic weights of the elements 2005 (IUPAC Technical Report)". Pure and Applied Chemistry. 78 (11): 2051–2066. doi:10.1351/pac200678112051. Lay summary.
- Half-life, spin, and isomer data selected from the following sources.
- Audi, Georges; Bersillon, Olivier; Blachot, Jean; Wapstra, Aaldert Hendrik (2003), "The NUBASE evaluation of nuclear and decay properties", Nuclear Physics A, 729: 3–128, Bibcode:2003NuPhA.729....3A, doi:10.1016/j.nuclphysa.2003.11.001
- National Nuclear Data Center. "NuDat 2.x database". Brookhaven National Laboratory.
- Holden, Norman E. (2004). "11. Table of the Isotopes". In Lide, David R. (ed.). CRC Handbook of Chemistry and Physics (85th ed.). Boca Raton, Florida: CRC Press. ISBN 978-0-8493-0485-9.