Svante Arrhenius

Svante August Arrhenius (/ɑːˈreɪniʊs/;[1] 19 February 1859 – 2 October 1927) was a Swedish scientist. Originally a physicist, but often referred to as a chemist, Arrhenius was one of the founders of the science of physical chemistry. He received the Nobel Prize for Chemistry in 1903, becoming the first Swedish Nobel laureate. In 1905, he became director of the Nobel Institute, where he remained until his death.[2]

Svante Arrhenius
Svante Arrhenius around 1910
Born	Svante August Arrhenius 19 February 1859 Wik Castle, Sweden, Sweden-Norway
Died	2 October 1927 (aged 68) Stockholm, Sweden
Nationality	Swedish
Alma mater	Uppsala University Stockholm University
Known for	Arrhenius equation Theory of ionic dissociation Acid-base theory Calculation of warming for double carbon dioxide in the atmosphere.
Awards	Davy Medal (1902) Nobel Prize for Chemistry (1903) ForMemRS (1910) Willard Gibbs Award (1911) Faraday Lectureship Prize (1914) Franklin Medal (1920)
Scientific career
Fields	Physics Chemistry
Institutions	Royal Institute of Technology
Doctoral advisor	Per Teodor Cleve Erik Edlund
Doctoral students	Oskar Benjamin Klein

Arrhenius was the first to use principles of physical chemistry to estimate the extent to which increases in atmospheric carbon dioxide are responsible for the Earth's increasing surface temperature. In the 1960s, Charles David Keeling demonstrated that the quantity of human-caused carbon dioxide emissions into the air is enough to cause global warming.[3]

The Arrhenius equation, Arrhenius acid, Arrhenius base, lunar crater Arrhenius, Martian crater Arrhenius,[4] the mountain of Arrheniusfjellet, and the Arrhenius Labs at Stockholm University were so named to commemorate his contributions to science.

Biography

Early years

Arrhenius was born on 19 February 1859 at Vik (also spelled Wik or Wijk), near Uppsala, Kingdom of Sweden, United Kingdoms of Sweden and Norway, the son of Svante Gustav and Carolina Thunberg Arrhenius. His father had been a land surveyor for Uppsala University, moving up to a supervisory position. At the age of three, Arrhenius taught himself to read without the encouragement of his parents, and by watching his father's addition of numbers in his account books, became an arithmetical prodigy. In later life, Arrhenius was profoundly passionate about mathematical concepts, data analysis and discovering their relationships and laws.

At age eight, he entered the local cathedral school, starting in the fifth grade, distinguishing himself in physics and mathematics, and graduating as the youngest and most able student in 1876.

Ionic disassociation

At the University of Uppsala, he was dissatisfied with the chief instructor of physics and the only faculty member who could have supervised him in chemistry, Per Teodor Cleve, so he left to study at the Physical Institute of the Swedish Academy of Sciences in Stockholm under the physicist Erik Edlund in 1881.

His work focused on the conductivities of electrolytes. In 1884, based on this work, he submitted a 150-page dissertation on electrolytic conductivity to Uppsala for the doctorate. It did not impress the professors, among whom was Cleve, and he received a fourth-class degree, but upon his defense it was reclassified as third-class. Later, extensions of this very work would earn him the 1903 Nobel Prize in Chemistry.[5]

Arrhenius put forth 56 theses in his 1884 dissertation, most of which would still be accepted today unchanged or with minor modifications. The most important idea in the dissertation was his explanation of the fact that solid crystalline salts disassociate into paired charged particles when dissolved, for which he would win the 1903 Nobel Prize in Chemistry. Arrhenius's explanation was that in forming a solution, the salt disassociates into charged particles, to which Michael Faraday had given the name ions many years earlier. Faraday's belief had been that ions were produced in the process of electrolysis, that is, an external direct current source of electricity was necessary to form ions. Arrhenius proposed that, even in the absence of an electric current, aqueous solutions of salts contained ions. He thus proposed that chemical reactions in solution were reactions between ions.[6][7][8]

The dissertation did not impress the professors at Uppsala, but Arrhenius sent it to a number of scientists in Europe who were developing the new science of physical chemistry, such as Rudolf Clausius, Wilhelm Ostwald, and J. H. van 't Hoff. They were far more impressed, and Ostwald even came to Uppsala to persuade Arrhenius to join his research team. Arrhenius declined, however, as he preferred to stay in Sweden-Norway for a while (his father was very ill and would die in 1885) and had received an appointment at Uppsala.[6][7][8]

In an extension of his ionic theory Arrhenius proposed definitions for acids and bases, in 1884. He believed that acids were substances that produce hydrogen ions in solution and that bases were substances that produce hydroxide ions in solution.

Middle period

Lehrbuch der kosmischen Physik, 1903

In 1885, Arrhenius next received a travel grant from the Swedish Academy of Sciences, which enabled him to study with Ostwald in Riga (now in Latvia), with Friedrich Kohlrausch in Würzburg, Germany, with Ludwig Boltzmann in Graz, Austria, and with van 't Hoff in Amsterdam.

In 1889, Arrhenius explained the fact that most reactions require added heat energy to proceed by formulating the concept of activation energy, an energy barrier that must be overcome before two molecules will react. The Arrhenius equation gives the quantitative basis of the relationship between the activation energy and the rate at which a reaction proceeds.

In 1891, he became a lecturer at the Stockholm University College (Stockholms Högskola, now Stockholm University), being promoted to professor of physics (with much opposition) in 1895, and rector in 1896.

Nobel Prizes

About 1900, Arrhenius became involved in setting up the Nobel Institutes and the Nobel Prizes. He was elected a member of the Royal Swedish Academy of Sciences in 1901. For the rest of his life, he would be a member of the Nobel Committee on Physics and a de facto member of the Nobel Committee on Chemistry. He used his positions to arrange prizes for his friends (Jacobus van't Hoff, Wilhelm Ostwald, Theodore Richards) and to attempt to deny them to his enemies (Paul Ehrlich, Walther Nernst, Dmitri Mendeleev).[9] In 1901 Arrhenius was elected to the Swedish Academy of Sciences, against strong opposition. In 1903 he became the first Swede to be awarded the Nobel Prize in chemistry. In 1905, upon the founding of the Nobel Institute for Physical Research at Stockholm, he was appointed rector of the institute, the position where he remained until retirement in 1927.

In 1911, he won the first Willard Gibbs Award.[10]

Society memberships

He was elected an Honorary Member of the Netherlands Chemical Society in 1909.[11]

He became a Foreign Member of the Royal Society (ForMemRS) in 1910.[12]

In 1912, he was elected a Foreign Honorary Member of the American Academy of Arts and Sciences[13]

In 1919, he became foreign member of the Royal Netherlands Academy of Arts and Sciences.[14]

Later years

Arrhenius family grave in Uppsala

Eventually, Arrhenius's theories became generally accepted and he turned to other scientific topics. In 1902, he began to investigate physiological problems in terms of chemical theory. He determined that reactions in living organisms and in the test tube followed the same laws.

In 1904, he delivered at the University of California a course of lectures, the object of which was to illustrate the application of the methods of physical chemistry to the study of the theory of toxins and antitoxins, and which were published in 1907 under the title Immunochemistry.[15] He also turned his attention to geology (the origin of ice ages), astronomy, physical cosmology, and astrophysics, accounting for the birth of the solar system by interstellar collision. He considered radiation pressure as accounting for comets, the solar corona, the aurora borealis, and zodiacal light.

He thought life might have been carried from planet to planet by the transport of spores, the theory now known as panspermia.[16] He thought of the idea of a universal language, proposing a modification of the English language.

He was a board member for the Swedish Society for Racial Hygiene (founded 1909), which endorsed mendelism at the time, and contributed to the topic of contraceptives around 1910. However, until 1938 information and sale of contraceptives was prohibited in the Kingdom of Sweden. Gordon Stein wrote that Svante Arrhenius was an atheist.[17][18] In his last years he wrote both textbooks and popular books, trying to emphasize the need for further work on the topics he discussed. In September 1927, he came down with an attack of acute intestinal catarrh and died on 2 October. He was buried in Uppsala.

Marriages and family

He was married twice, first to his former pupil Sofia Rudbeck (1894 to 1896), with whom he had one son, Olof Arrhenius, and then to Maria Johansson (1905 to 1927), with whom he had two daughters and a son.

Arrhenius was the grandfather of bacteriologist Agnes Wold,[19] chemist Svante Wold,[20] and ocean biogeochemist Gustaf Arrhenius.[21]

Greenhouse effect

In developing a theory to explain the ice ages, Arrhenius, in 1896, was the first to use basic principles of physical chemistry to calculate estimates of the extent to which increases in atmospheric carbon dioxide (CO₂) will increase Earth's surface temperature through the greenhouse effect.[3][22][23] These calculations led him to conclude that human-caused CO₂ emissions, from fossil-fuel burning and other combustion processes, are large enough to cause global warming. This conclusion has been extensively tested, winning a place at the core of modern climate science.[24][25] Arrhenius, in this work, built upon the prior work of other famous scientists, including Joseph Fourier, John Tyndall and Claude Pouillet. Arrhenius wanted to determine whether greenhouse gases could contribute to the explanation of the temperature variation between glacial and inter-glacial periods.[26] Arrhenius used infrared observations of the moon – by Frank Washington Very and Samuel Pierpont Langley at the Allegheny Observatory in Pittsburgh – to calculate how much of infrared (heat) radiation is captured by CO₂ and water (H₂O) vapour in Earth's atmosphere. Using 'Stefan's law' (better known as the Stefan–Boltzmann law), he formulated what he referred to as a 'rule'. In its original form, Arrhenius's rule reads as follows:

if the quantity of carbonic acid increases in geometric progression, the augmentation of the temperature will increase nearly in arithmetic progression.

Here, Arrhenius refers to CO₂ as carbonic acid (which refers only to the aqueous form H₂CO₃ in modern usage). The following formulation of Arrhenius's rule is still in use today:[27]

${\displaystyle \Delta F=\alpha \ln(C/C_{0})}$

where ${\displaystyle C_{0}}$ is the concentration of CO₂ at the beginning (time-zero) of the period being studied (if the same concentration unit is used for both ${\displaystyle C}$ and ${\displaystyle C_{0}}$, then it doesn't matter which concentration unit is used); ${\displaystyle C}$ is the CO₂ concentration at end of the period being studied; ln is the natural logarithm (= log base e (log_e)); and ${\displaystyle \Delta F}$ is the augmentation of the temperature, in other words the change in the rate of heating Earth's surface (radiative forcing), which is measured in Watts per square meter.[27] Derivations from atmospheric radiative transfer models have found that ${\displaystyle \alpha }$ (alpha) for CO₂ is 5.35 (± 10%) W/m² for Earth's atmosphere.[28]

Arrhenius at the first Solvay conference on chemistry in 1922 in Brussels.

Based on information from his colleague Arvid Högbom, Arrhenius was the first person to predict that emissions of carbon dioxide from the burning of fossil fuels and other combustion processes were large enough to cause global warming. In his calculation Arrhenius included the feedback from changes in water vapor as well as latitudinal effects, but he omitted clouds, convection of heat upward in the atmosphere, and other essential factors. His work is currently seen less as an accurate quantification of global warming than as the first demonstration that increases in atmospheric CO₂ will cause global warming, everything else being equal.

Svante Arrhenius (1909)

Arrhenius's absorption values for CO₂ and his conclusions met criticism by Knut Ångström in 1900, who published the first modern infrared absorption spectrum of CO₂ with two absorption bands, and published experimental results that seemed to show that absorption of infrared radiation by the gas in the atmosphere was already "saturated" so that adding more could make no difference. Arrhenius replied strongly in 1901 (Annalen der Physik), dismissing the critique altogether. He touched on the subject briefly in a technical book titled Lehrbuch der kosmischen Physik (1903). He later wrote Världarnas utveckling (1906) (German: Das Werden der Welten [1907], English: Worlds in the Making [1908]) directed at a general audience, where he suggested that the human emission of CO₂ would be strong enough to prevent the world from entering a new ice age, and that a warmer earth would be needed to feed the rapidly increasing population:

"To a certain extent the temperature of the earth's surface, as we shall presently see, is conditioned by the properties of the atmosphere surrounding it, and particularly by the permeability of the latter for the rays of heat." (p. 46)

"That the atmospheric envelopes limit the heat losses from the planets had been suggested about 1800 by the great French physicist Fourier. His ideas were further developed afterwards by Pouillet and Tyndall. Their theory has been styled the hot-house theory, because they thought that the atmosphere acted after the manner of the glass panes of hot-houses." (p. 51)

"If the quantity of carbonic acid [ CO₂ + H₂O → H₂CO₃ (carbonic acid) ] in the air should sink to one-half its present percentage, the temperature would fall by about 4°; a diminution to one-quarter would reduce the temperature by 8°. On the other hand, any doubling of the percentage of carbon dioxide in the air would raise the temperature of the earth's surface by 4°; and if the carbon dioxide were increased fourfold, the temperature would rise by 8°." (p. 53)

"Although the sea, by absorbing carbonic acid, acts as a regulator of huge capacity, which takes up about five-sixths of the produced carbonic acid, we yet recognize that the slight percentage of carbonic acid in the atmosphere may by the advances of industry be changed to a noticeable degree in the course of a few centuries." (p. 54)

"Since, now, warm ages have alternated with glacial periods, even after man appeared on the earth, we have to ask ourselves: Is it probable that we shall in the coming geological ages be visited by a new ice period that will drive us from our temperate countries into the hotter climates of Africa? There does not appear to be much ground for such an apprehension. The enormous combustion of coal by our industrial establishments suffices to increase the percentage of carbon dioxide in the air to a perceptible degree." (p. 61)

"We often hear lamentations that the coal stored up in the earth is wasted by the present generation without any thought of the future, and we are terrified by the awful destruction of life and property which has followed the volcanic eruptions of our days. We may find a kind of consolation in the consideration that here, as in every other case, there is good mixed with the evil. By the influence of the increasing percentage of carbonic acid in the atmosphere, we may hope to enjoy ages with more equable and better climates, especially as regards the colder regions of the earth, ages when the earth will bring forth much more abundant crops than at present, for the benefit of rapidly propagating mankind." (p. 63)

At this time, the accepted consensus explanation is that, historically, orbital forcing has set the timing for ice ages, with CO₂ acting as an essential amplifying feedback.[29][30] However, CO₂ releases since the industrial revolution have increased CO₂ to a level not found since 10 to 15 million years ago, when the global average surface temperature was up to 11 °F (6 °C) warmer than now and almost all ice had melted, raising world sea-levels to about 100 feet higher than today's.[31]

Arrhenius estimated based on the CO₂ levels at his time, that reducing levels by 0.62–0.55 would decrease temperatures by 4–5 °C (Celsius) and an increase of 2.5 to 3 times of CO₂ would cause a temperature rise of 8–9 °C in the Arctic.[22][32] In his book Worlds in the Making he described the "hot-house" theory of the atmosphere.[33]

Works

• 1884, Recherches sur la conductivité galvanique des électrolytes, doctoral dissertation, Stockholm, Royal publishing house, P. A. Norstedt & söner, 89 pages.
• 1896a, Ueber den Einfluss des Atmosphärischen Kohlensäurengehalts auf die Temperatur der Erdoberfläche, in the Proceedings of the Royal Swedish Academy of Science, Stockholm 1896, Volume 22, I N. 1, pages 1–101.
• 1896b, On the Influence of Carbonic Acid in the Air upon the Temperature of the Ground, London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science (fifth series), April 1896. vol 41, pages 237–275.
• 1901a, Ueber die Wärmeabsorption durch Kohlensäure, Annalen der Physik, Vol 4, 1901, pages 690–705.
• 1901b, Über Die Wärmeabsorption Durch Kohlensäure Und Ihren Einfluss Auf Die Temperatur Der Erdoberfläche. Abstract of the proceedings of the Royal Academy of Science, 58, 25–58.
• Arrhenius, Svante. Die Verbreitung des Lebens im Weltenraum. Die Umschau, Frankfurt a. M., 7, 1903, 481–486.
• Lehrbuch der kosmischen Physik (in German). 1. Leipzig: Hirzel. 1903.
  • Lehrbuch der kosmischen Physik (in German). 2. Leipzig: Hirzel. 1903.
• 1906, Die vermutliche Ursache der Klimaschwankungen, Meddelanden från K. Vetenskapsakademiens Nobelinstitut, Vol 1 No 2, pages 1–10
• 1908, Das Werden der Welten (Worlds in the making; the evolution of the universe), Academic Publishing House, Leipzig, 208 pages.

See also

• Acid–base reaction
• History of climate change science
• James Croll
• Eunice Newton Foote
• George Perkins Marsh
• Milutin Milanković
• Greta Thunberg – climate activist and distant relative of Arrhenius[34]

References

1. "Arrhenius". Webster’s New World College Dictionary.
2. "Arrhenius, Svante August" in Chambers's Encyclopædia. London: George Newnes, 1961, Vol. 1, p. 635.
3. Baum, Sr., Rudy M. (2016). "Future Calculations: The first climate change believer". Distillations. 2 (2): 38–39. Retrieved 22 March 2018.
4. de Vaucouleurs, G.; et al. (September 1975). "The new Martian nomenclature of the International Astronomical Union". Icarus. 26 (1): 85−98. Bibcode:1975Icar...26...85D. doi:10.1016/0019-1035(75)90146-3.
5. "The Nobel Prize in Chemistry 1903". www.nobelprize.org. Retrieved 18 March 2018.
6. Harris, William; Levey, Judith, eds. (1975). The New Columbia Encyclopedia (4th ed.). New York City: Columbia University. p. 155. ISBN 978-0-231035-729.
7. McHenry, Charles, ed. (1992). The New Encyclopædia Britannica. 1 (15 ed.). Chicago: Encyclopædia Britannica, Inc. p. 587. ISBN 978-085-229553-3.
8. Cillispie, Charles, ed. (1970). Dictionary of Scientific Biography (1 ed.). New York City: Charles Scribner's Sons. pp. 296–302. ISBN 978-0-684101-125.
9. Patrick Coffey, Cathedrals of Science: The Personalities and Rivalries That Made Modern Chemistry, Oxford University Press, 2008,
10. "Willard Gibbs Award". chicagoacs.org. Retrieved 18 March 2018.
11. Honorary members - website of the Royal Netherlands Chemical Society
12. Royal Society. "Fellows of the Royal Society".
13. "Book of Members, 1780–2010: Chapter A" (PDF). American Academy of Arts and Sciences. Archived from the original (PDF) on 18 June 2006. Retrieved 25 April 2011. Page 14, third column, on the right.
14. "Svante August Arrhenius (1859–1927)". Royal Netherlands Academy of Arts and Sciences. Retrieved 19 July 2015.
15. Svante Arrhenius (1907). Immunochemistry; the application of the principles of physical chemistry to the study of the biological antibodies. The Macmillan Company.
16. Arrhenius, S., Worlds in the Making: The Evolution of the Universe. New York, Harper & Row, 1908,
17. Gordon Stein (1988). The encyclopedia of unbelief. 1. Prometheus Books. p. 594. ISBN 9780879753078. Svante Arrhenius (I859-I927), recipient of the Nobel Prize in chemistry (I903), was a declared atheist and the author of The Evolution of the Worlds and other works on cosmic physics.
18. NNDB.com. "Svante Arrhenius". Soylent Communications. Retrieved 11 September 2012.
19. Mot bacillskräck och gubbvälde, 1 February 2011
20. "Svante Wold". www.umu.se (in Swedish).
21. Arrhenius, O. (January 1923). "Statistical Investigations in the Constitution of Plant Associations". Ecology. 4 (1): 68–73. doi:10.2307/1929275. JSTOR 1929275.
22. Arrhenius, Svante (1896). "On the influence of carbonic acid in the air upon the temperature of the ground" (PDF). The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science. 41 (251): 237–276. doi:10.1080/14786449608620846.
23. Arrhenius, Svante (1897). "On the Influence of Carbonic Acid in the Air Upon the Temperature of the Ground". Publications of the Astronomical Society of the Pacific. 9 (54): 14. Bibcode:1897PASP....9...14A. doi:10.1086/121158.
24. "How do we know more CO2 is causing global warming?", Skeptical Science, founded by John Cook, the Climate Communication Fellow for the Global Change Institute, University of Queensland, Brisbane, Australia
25. "Climate Change 2013 – The Physical Science Basis, by the Intergovernmental Panel on Climate Change (IPCC)", IPCC, 2013: Summary for Policymakers. In: Climate Change 2013: The Physical Science Basis. Contribution of Working Group I to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change [Stocker, T.F., D. Qin, G.-K. Plattner, M. Tignor, S.K. Allen, J. Boschung, A. Nauels, Y. Xia, V. Bex and P.M. Midgley (eds.)]. Cambridge University Press, Cambridge, England and New York, NY.
26. Rodhe, Henning, et al. "Svante Arrhenius and the Greenhouse Effect". Ambio, vol. 26, no. 1, 1997, pp. 2–5. JSTOR 4314542.
27. Martin E. Walter, "Earthquakes and Weatherquakes: Mathematics and Climate Change", Notices of the American Mathematical Society, Volume 57, Number 10, p. 1278 (November 2010).
28. "NOAA Annual Greenhouse Gas Index, Spring 2016", NOAA Annual Greenhouse Gas Index, NOAA Earth System Research Laboratory, Boulder, CO, James H Butler and Stephen A Montzka
29. Monroe, Rob (20 June 2014). "How do CO2 levels relate to ice ages and sea-level?". The Keeling Curve. Retrieved 19 December 2019.
30. Ganopolski, A.; Calov, R. (2011). "The role of orbital forcing, carbon dioxide and regolith in 100 kyr glacial cycles" (PDF). Climate of the Past. 7 (4): 1415–1425. Bibcode:2011CliPa...7.1415G. doi:10.5194/cp-7-1415-2011.
31. Andrew Freedman. "The Last Time CO2 Was This High, Humans Didn't Exist". www.climatecentral.org. Retrieved 19 December 2019.
32. NASA. "Svante Arrhenius".
33. NASA. "Svante Arrhenius".
34. Ernman, Beata; Ernman, Malena; Thunberg, Greta; Thunberg, Svante. Our House is on Fire: Scenes of a Family and a Planet in Crisis. p. 152. ISBN 9780525507376.

Further reading

• Snelders, H. A. M. (1970). "Arrhenius, Svante August". Dictionary of Scientific Biography. 1. New York: Charles Scribner's Sons. pp. 296–301. ISBN 978-0-684-10114-9.
• Crawford, Elisabeth T. (1996). Arrhenius: from ionic theory to the greenhouse effect. Canton, MA: Science History Publications. ISBN 978-0-88135-166-8.
• Coffey, Patrick (2008). Cathedrals of Science: The Personalities and Rivalries That Made Modern Chemistry. Oxford University Press. ISBN 978-0-19-532134-0.

External links

• Works by Svante Arrhenius at Project Gutenberg
• Svante Arrhenius on Nobelprize.org including the Nobel Lecture, December 11, 1903 Development of the Theory of Electrolytic Dissociation
• A Tribute to the Memory of Svante Arrhenius (1859–1927) – a scientist ahead of his time, published in 2008 by the Royal Swedish Academy of Engineering Sciences
• Svante Arrhenius (1859–1927)
• Obs 50 (1927) 363 – Obituary (one paragraph)
• PASP 39 (1927) 385 – Obituary (one paragraph)
• "On the influence of Carbonic Acid in the Air upon the Temperature of the Ground", Arrhenius, 1896, online and analyzed on BibNum [click 'à télécharger' for English analysis]
• Newspaper clippings about Svante Arrhenius in the 20th Century Press Archives of the ZBW